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The spin only magnetic moment value of [...

The spin only magnetic moment value of `[MnBr_(4)]^(2-)` ion is `5.9BM` On the basis of `VBT` Predict the hybridisation and geometry of `[MnBr_(4)]^(2-)` ion ` .

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Since the coordination number of `Mn^(2+)` ion in the complex ion is 4, it will be either tetrahedral (`sp^(3)` hybridisation) or square planar `(dsp^(2)` hybridisation). But the fact that the magnetic moment of the complex ion is 5.9 BM, it should be tetrahedral in shape rather than square planar because of the presence of five unpaired electrons in the d orbitals.
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NCERT-COORDINATION COMPOUNDS-Exercise
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  2. Wrtie the formulas for the following coordination compounds: (i). Te...

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  3. Write the IUPAC names of the following coordiantion compounds: (i) [...

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  4. Indicate the type of isomerism exhibited by the following complexes an...

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  5. Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl are ionisation ...

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  6. Deduce the structures of [NiCl(4)]^(2-) and [Ni (CN)(4)]^(2-) consider...

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  7. [NiCl(4)]^(2-) is paramagnetic while [Ni(CO)(4)] is diamagnetic though...

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  8. [Fe(H2O)6]^(3+) is strongly paramagnetic whereas [Fe(CN)6]^(3-) is wea...

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  9. Explain [Co(NH3)6]^(3+) is an inner orbital complex whereas [Ni(NH3)6]...

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  10. Predict the number of unpaired electrons in the square planar [Pt(CN)4...

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  11. The hexaquo manganese(II) ion contains five unpaired electrons, while ...

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  12. WERNER’S THEORY OF COORDINATION COMPOUNDS

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  13. FeSO4 solution mixed with (NH4)2SO4 solution is 1:1 molar ratio gives ...

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  14. Explain with two examples each of the following: coordination entity, ...

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  15. What is meant by unidentate and ambidentate ligands? Give two examples...

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  16. Specify the oxidation numbers of the metals in the following coordinat...

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  17. Using IUPAC norms write the fomulas for the following (i). Tetrahydr...

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  18. Using IUPAC norms write the systematic names of the following: (i). ...

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  19. List various types of isomerism possible for coordination compounds, g...

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  20. How many geometrical isomers are possible in the following corrdinatio...

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  21. Draw the structures of optical isomers of: (i). [Cr(C2O4)3]^(3-) (...

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