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H(3)C-C=Choverset(1.NaNH(2))underset(2.C...

`H_(3)C-C=Choverset(1.NaNH_(2))underset(2.CH_(3)CH_(2)Br)rarrAoverset(H_(2))underset(Pd-BaSO_(4)B:`

A

`A is H_(3)C-CH_(2)-C=CH`

B

A is `CH_(3)-C-=C-CH_(2)CH_(3)`

C

D

Text Solution

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The correct Answer is:
B, C
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Identify (X), (Y) and (Z) in the following synthetic scheme and write their structures. CH_(3)CH_(3) -C-=Choverset(i) NaNH_(2)underset(CH_(3)CH_(2)Br) to (X) overset(H_(2)//Pd-BaSO_(4))to (Y) overset("alkaline"KMnO_(4))to(Z) Is the compound (Z) optically active? Justify your answer.

CH-=CHoverset(NaNH_(2))to[A]overset(CH_(3)Br)to[B]

In the reaction H-C-=CHoverset((1)NaNH_(2)//liq.NH_(3))underset((2)CH_(3)CH_(2)Br)rarr X, overset((i)NaNH_(2)//liq. NH_(3))underset((2)CH_(3)CH_(2)Br)rarr Y X and Y are :

What is the final major product of the following reaction CH_(3) - CH_(2) - C = C - H overset(NaNH_(2)) to overset(CH_(3) CH_(2) CH_(2) - Br) to overset(Hg SO_(4)) underset(H_(2) SO_(4))to ?

overset ((i)NaNH_(2),NH_(3)) underset((ii)CH_(3)Br)to (A) overset (H_(2)) underset ("Lindlar catalyst ") to (B) ,

HC-=CHoverset(HgSO_(4)//H_(2)SO_(4))rarr[A]overset("Oxidation")rarr[B]overset(PCl_(5))rarr[C]overset(H_(2))underset(Pd//BaSO_(4))rarr[D]underset(H_(3)O^(+))overset(CH_(3)MgBr)rarr[E]

Write the IUPAC name of the following compound. overset(5)(C)H_(3)-overset(4)(C)H_(2)-underset(CH_(3))underset(|)overset(3)(C)H-underset(CH_(3))underset(|)overset(CH_(3))overset (2|)(C)-overset(1)(C)H_(3) overset(1)(C)H_(3)-overset(2)(C)H_(2)-overset(3)(C)H_(2)-overset(4)(C)H_(2)-underset(CH_(3))underset(3|)underset(CH-CH_(3))underset(2|)underset(CH-CH_(3))underset(1|)overset(6)(CH)-overset(6)(C)H_(2)-overset(7)(C)H_(2)-overset(8)(C)H_(2)-overset(9)(C)H_(3)

HIMANSHU PANDEY-HYDROCARBONS (ALKANE, ALKENE and ALKYNE)-More Than One Correct (Q.26 To Q.50)
  1. H(3)C-C=Choverset(1.NaNH(2))underset(2.CH(3)CH(2)Br)rarrAoverset(H(2))...

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  2. H(3)C=C=Choverset(Hg^(+2)//H(2)SO(4))rarrXoverst(KMnO(4))rarrY:

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  3. H(3)C-C=Choverset(NaNH(2))rarrXoverset(Acetone)underset(H(2)O)rarrYove...

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  4. Complete the following reaction

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  5. Which of the following solubility orders in water are correct ?

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  6. Complete the following reaction

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  7. Write the product of the following reaction:

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  8. Complete the following reaction

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  9. Complete the following reaction

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  10. Which of the folllowing carbocations would you expect to rearrange?

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  11. Select the correct statements:

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  12. Which o fthe following will give allyl halide?

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  13. Which of the following reactions will give least substituted alkene?

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  14. Which of the following reactions will give alkyne?

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  15. An organic compound on reaction with O(3) followed by Zn and H(2)Ogive...

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  16. Which of the following reactions are correctly represented?

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  17. Which of the following give allylic substitution product?

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  18. Which of the following reactions are correct ?

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  19. Which of the following are correct for the addition of X(2) on a alken...

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  20. Which of the following will react with I-butyne?

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