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A(s)hArrH(2)S(g)+B(g) At eq., pressure =...

`A(s)hArrH_(2)S(g)+B(g)` At eq., pressure = 18 atm
`C(s)hArrH_(2)S(g)+D(g)` At eq., pressure = 36 atm
Calculation
total pressure at new equilibrium when both the solids are heated simultaneously

Text Solution

Verified by Experts

`A(s)hArrunderset(x+y x)( H_(2)S(g))+B(g),K_(p_(1))=(9)^(2)=81`
`C(s)hArrunderset(x+y y)(H_(2)S(g))+D(g),K_(p_(2))=(18)^(2)=324`
total pressure `= x + y + x + y = 2 (x + y)`
`K_(p_(1))+k_(p_(2))=(x+y)^(2)rArrx+y=sqrt(k_(p_(1))+k_(p_(2)))`
`rArr` total pressure `= 2 (x + y) = 2sqrt(K_(p_(1))+k_(p_(2)))`
`=2sqrt(81+324)=2sqrt(405)` atm
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MOTION-CHEMICAL EQUILIBRIUM-Exercise - 4
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  2. For the reaction, 2NO(2(g))hArr2NO((g)) + O(2(g)) K(c) = 1.0xx10^(-6) ...

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  3. The exothermic formation of ClF(3) is represented by thr equation: C...

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  4. A schematic plot of ln K(eq) versus inverse of temperature for a react...

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  5. An amount of solid NH4HS is placed in a flask already containing ammon...

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  6. Phosphorus pentachloride dissociates as follows, ina closed reaction v...

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  7. The equilibrium constant for the given reaction: SO(3(g))hArrSO(2(g)...

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  8. For the following three reaction 1, 2 and 3, equilibrium constants are...

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  9. The equilibrium constant K(p(1)) and K(p(2)) for the reactions XhArr2Y...

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  10. A vessel at 1000 K contains carbon dioxide with a pressure of 0.5 atm....

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  11. The equilibrium constant for the reaction N(2)(g)+O(2)(g) hArr 2NO(g...

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  12. For the reaction, SO(2)(g)+1/2O(2)(g)hArrSO(3)(g) if K(p)=K(C)(RT)^(x)...

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  13. The standard Gibbs energy change at 300K for the reaction 2AhArrB+C is...

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  14. The equilibrium constant at 298K for a reaction, A+BhArrC+D is 100. If...

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  15. Which of the following lines correctly show the temperature dependence...

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  16. If Ag^(+)+NH(3)hArr[Ag(NH(3))]^(+), K(1)=3.5xx10^(-3) and [Ag(NH(3))]^...

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  17. The thermal dissociation of equilibrium of CaCo(3)(s) is studied under...

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  18. For the reaction, SO(2)(g)+1/2O(2)(g)hArrSO(3)(g) if K(p)=K(C)(RT)^(x)...

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  19. The % yield of ammonia as a function of time in the reaction N(2)(g) +...

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  20. Thermal decomposition of gaseous X(2) to gaseous X at 298 K takes plac...

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  21. Thermal decomposition of gaseous X(2) to gaseous X at 298 K takes plac...

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