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If Ag^(+)+NH(3)hArr[Ag(NH(3))]^(+), K(1)...

If `Ag^(+)+NH_(3)hArr[Ag(NH_(3))]^(+)`, `K_(1)=3.5xx10^(-3)` and `[Ag(NH_(3))]^(+)+NH_(3)hArr[Ag(NH_(3))_(2)]^(+)`, `K_(2)=1.74xx10^(-3)`. The formation constant of `[Ag(NH_(3))_(2)]^(+)` is :

A

`6.08xx10^(-6)`

B

`6.8xx10^(-6)`

C

`1.6xx10^(3)`

D

`1.088xx10^(7)`

Text Solution

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The correct Answer is:
D
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Ag^(+)+NHP(3)hArr[Ag(NH_(3))]^(+), K_(1)=3.5=10^(-3) [Ag(NH)_(3)]^(+)+NH_(3)hArr[Ag(NH_(3))_(2)]^(+),K_(2)=1.7xx10^(-3) then the formation constant of [Ag(NH_(3))_(2)]^(+) is

Ag^(+)+hArr|Ag(NH_(3))_(2)|^(+), k_(1) = 6.8 xx 10^(-3) [Ag(NH_(3))]^(+) + NH_(3)hArr |Ag(NH_(3))_(2)|, k_(2) = 1.6xx10^(-3) Then the formation constant or |Ag(NH_(3))_(2)|^(+) is

Ag^(+) + NH_(3) ltimplies [Ag(NH_(3))]^(+), k_(1)=6.8 xx 10^(-5) [Ag(NH_(3))]^(+) + NH_(3) ltimplies [Ag(NH_(3))_(2)]^(+) , k_(2) = 1.6xx10^(-3) The formation constant of [Ag(NH_(3))_(2)]^(+) is :

{:(Ag^+ +NH_3 hArr[Ag(NH_3)]^+,,K_1=3.5xx10^-3),([Ag(NH_3)]^+ +NH_3 hArr[Ag(NH_3)_2]^+,,K_2=1.8xx10^-3):} then, the overall formation constant of [Ag(NH_3)_2]^+ is :

Zn^(+2) + 2NH_(3) hArr [Zn(NH_(3))_(2)]^(+2), K_(1) = 2xx10^(-3) [Zn(NH_(3))_(2)]^(+2) + 2NH_(3) hArr [Zn(NH_(3))_(4)]^(2+), K_(2) = 1.5xx10^(-3) Find out the instability constant?

The hybridisation of Ag in [Ag(NH_3)_2]^(+) complex is

MOTION-CHEMICAL EQUILIBRIUM-Exercise - 4
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  2. The exothermic formation of ClF(3) is represented by thr equation: C...

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  3. A schematic plot of ln K(eq) versus inverse of temperature for a react...

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  4. An amount of solid NH4HS is placed in a flask already containing ammon...

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  5. Phosphorus pentachloride dissociates as follows, ina closed reaction v...

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  6. The equilibrium constant for the given reaction: SO(3(g))hArrSO(2(g)...

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  7. For the following three reaction 1, 2 and 3, equilibrium constants are...

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  8. The equilibrium constant K(p(1)) and K(p(2)) for the reactions XhArr2Y...

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  9. A vessel at 1000 K contains carbon dioxide with a pressure of 0.5 atm....

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  10. The equilibrium constant for the reaction N(2)(g)+O(2)(g) hArr 2NO(g...

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  11. For the reaction, SO(2)(g)+1/2O(2)(g)hArrSO(3)(g) if K(p)=K(C)(RT)^(x)...

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  12. The standard Gibbs energy change at 300K for the reaction 2AhArrB+C is...

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  13. The equilibrium constant at 298K for a reaction, A+BhArrC+D is 100. If...

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  14. Which of the following lines correctly show the temperature dependence...

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  15. If Ag^(+)+NH(3)hArr[Ag(NH(3))]^(+), K(1)=3.5xx10^(-3) and [Ag(NH(3))]^...

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  16. The thermal dissociation of equilibrium of CaCo(3)(s) is studied under...

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  17. For the reaction, SO(2)(g)+1/2O(2)(g)hArrSO(3)(g) if K(p)=K(C)(RT)^(x)...

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  18. The % yield of ammonia as a function of time in the reaction N(2)(g) +...

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  19. Thermal decomposition of gaseous X(2) to gaseous X at 298 K takes plac...

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  20. Thermal decomposition of gaseous X(2) to gaseous X at 298 K takes plac...

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