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Fe^(3+)overset(SCN^(-) ("excess"))rarr "...

`Fe^(3+)overset(SCN^(-) ("excess"))rarr "Blood red (A)" overset(F^(-)("excess"))rarr "Colourless (B)"`
Identify A and B.
(i) Write IUPAC name of A and B.
(ii) Find out spin only magnetic moment of B.

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Verified by Experts

The correct Answer is:
`A=[Fe(SCN)(H_(2)O)_(5)]^(2+), M M=sqrt(35)`
Pentaaquathiocynanato-S-iron (III) iron
`B=[FeF_(6)]^(3-), M M=sqrt(35)`
hexaflouroferrate (III) ion
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Fe^(3+)overset(SCN^-)underset( excess )rarrAoverset(F^-)underset( excess)rarrB What are A and B ? Give IUPAC names of A and B .Find spin only magnetic moment of B .

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Knowledge Check

  • (A)overset(CI_(2)//\h2)rarr (B) overset(aq.KOH)rarr(C)overset([O])rarr CH_(3) CHO Identify A,B and C .

    A
    Ethyl alcohol, Ethyl chloride and Ethane
    B
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    C
    Propane Propyl chloride and Propyl alcohol
    D
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    A
    `( CH_(3))_(2) C( OH ) CN, ( CH_(3))_(2)C( OH ) COOH`
    B
    `( CH_(3))_(2)C(OH) CN, ( CH_(3))_(2)C ( OH)_(2)`
    C
    `( CH_(3))_(2)C(OH)CN,(CH_(3))_(2)CHCOOH`
    D
    `(CH_(3))_(2)C(OH)CN, ( CH_(3))_(2)C=O`
  • CHCl_(3)+MeCOMe overset(OH^(-))rarr A overset("excess KOH")rarr B overset(NaOH - CaO)rarr C overset("KOBr")rarr D

    A
    `MeCH_(2)OH`
    B
    `MeCOOH`
    C
    `Me_(2)CHOH`
    D
    `CH_(2)Cl_(2)`
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