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KO(2) exhibits paramagnetic behaviour. T...

`KO_(2)` exhibits paramagnetic behaviour. This is due to the paramagnetic nature of

A

`KO^(-)`

B

`K^(+)`

C

`O_(2)`

D

Oi

Text Solution

Verified by Experts

The correct Answer is:
d

Oxygen in KO, exists as `O_(2)` ion
According to molecular orbital theory `O_(2)^(-)` consists of an unpaired `e^(-)` in anti-bonding orbital
`O_(2)^(-)= sigma1s^(2), sigma1s^(2), sigma2s^(2), sigma2s^(2), sigma2p_(z)^(2), pi 2p_(z)^(2) approx. pi^(2)p_(y)^(2),pi 2 p_(y)^(2)=overset(*)(pi)2p_(y)^(2)= overset(*)(pi)2p_(y)^(1)`
Hence, `KO_(2)` is paramagnetic in nature.
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