Home
Class 12
CHEMISTRY
The condition for a reaction to occur sp...

The condition for a reaction to occur spontaneously is -

A

`DeltaH` must be negative

B

`DeltaS` must be netagive

C

`(DeltaH-TDeltaS)` must be negative

D

`(DeltaH+TDeltaS)` must be negative.

Text Solution

Verified by Experts

The correct Answer is:
C

At constant temperature and pressure, for a spontaneous process of the reaction `Delta G lt0`. According to Gibbs equation `DeltaG=DeltaH-TDeltaS`. Therefore the condition of spontaneity is, `DeltaH-TDeltaS lt0`.
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise MCQ HOTSPOT (SINGLE CORRENT TYPE)|71 Videos
  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise VERY SHORT TYPE QUESTIONS|53 Videos
  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise HIGHER ORDER THINKING SKILLS (HOTS) QUESTIONS|20 Videos
  • CHEMICAL KINETICS

    CHHAYA PUBLICATION|Exercise EXERCISE (NUMERICAL PROBLEMS)|37 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    CHHAYA PUBLICATION|Exercise PRACTICE SET 15|15 Videos

Similar Questions

Explore conceptually related problems

A reaction occurs spontaneously if

If the value of DeltaH and DeltaS are of following type, then at what condition a reaction will occur spontaneously? (i) DeltaH gt0 and DeltaSgt0 (ii) DeltaH lt0 and DeltaS gt0

Under which of the following conditions a reaction will occur spontaneously? (i) DeltaH lt0 and DeltaS lt0 (ii) DeltaH gt0 and DeltaS lt0 .

For a reaction both Delta H and Delta S are positive,under what condition will the reaction occur spontaneously?

Given : E_(Ni^(2+)|Ni)^(@)=-0.25V, E_(Zn^(2+)|Zn)^(@)=-0.76V, E_(Cu^(2+)|Cu)^(@)=+0.34V, E_(Ag^(+)|Ag)^(@)=+0.8V . Under standard conditions, which reaction(s) will occur spontaneously -

Hill reaction occurs in

Hill reactions occurs in

Are the given statements correct? (1) if heat is absorbed in a chemical reaction, the reaction cannot be spontaneous. (2) the entropy of the system may decrease in a reaction, but the reaction can occur spontaneously.

The given redox reactions occur spontaneously Arrange Ag,Zn and Cu according to their increasing standard reduction potentials .

The entropy of the system decreases on condensation of a vapour though it occurs spontaneously. Explain.

CHHAYA PUBLICATION-CHEMICAL THERMODYNAMICS-ENTRANCE QUESTION BANK
  1. For the reaction X(2)Y(4)(l) to 2XY(g) at 300K the values of DeltaU an...

    Text Solution

    |

  2. For the reaction 2SO(2)(g)+O(2)(g)hArr2SO(3)(g) at 300K, value of Delt...

    Text Solution

    |

  3. The condition for a reaction to occur spontaneously is -

    Text Solution

    |

  4. During a reversible adiabatic process, the pressure of a gas is found ...

    Text Solution

    |

  5. The heat of neutralisation of a strong base and a strong acid is 13.7 ...

    Text Solution

    |

  6. The entropy change involved in the isothermal reversible expansion of ...

    Text Solution

    |

  7. Among the following expressions which one is incorrect-

    Text Solution

    |

  8. A cylinder filled with 0.04 mol of ideal gas expands reversible from 5...

    Text Solution

    |

  9. For complete combustion of enthanol, C(2)H(5)OH(l)+3O(2)(g)to2CO(2)(...

    Text Solution

    |

  10. The following reaction is performed free energy of formation of NO(g) ...

    Text Solution

    |

  11. The standard Gibbs energy change at 300K for the reaction 2A hArr B+C ...

    Text Solution

    |

  12. The heats of combustion of carbon and carbon monoxide are -393.5 and -...

    Text Solution

    |

  13. Given, C(graphite)+O(2)(g)toCO(2)(g),Delta(r)H^(0)=-393.5kJ*mol^(-1) ...

    Text Solution

    |

  14. The combustion of benzene (l) gives CO(2)(g) and H(2)O(l). Given that ...

    Text Solution

    |

  15. If (1)/(2)AtoB,DeltaH=+150kJ*mol^(-1),3B to 2C+D,DeltaH=-125kJ*mol^(-1...

    Text Solution

    |

  16. Which is correct option for free expansion of an ideal gas under adiab...

    Text Solution

    |

  17. Enthalpy change for the reaction, 4H(g) to 2H(2)(g) is -869.5kJ. The d...

    Text Solution

    |

  18. If the enthalpy change for the transition of liquid water to steam is ...

    Text Solution

    |

  19. In which of the given reactions, standard reaction entropy change (Del...

    Text Solution

    |

  20. For the reaction, X(2)O(4)(l)to2XO(2)(g),DeltaU=2.1 kcal, DeltaS=20cal...

    Text Solution

    |