Home
Class 12
CHEMISTRY
Among the following expressions which on...

Among the following expressions which one is incorrect-

A

`w_("rev, iso")=-nRT"ln"(V_(f))/(V_(i))`

B

`"ln K"=(DeltaH^(0)-TDeltaS^(0))/(RT)`

C

`K=e^(-DeltaG^(0)//RT)`

D

`(DeltaG_(sys))/(DeltaS_("total"))=-T`

Text Solution

Verified by Experts

The correct Answer is:
B

`DeltaG^(0)=-RTlnK and DeltaG^(0)=DeltaH^(0)-TDeltaS^(0)`.
`therefore H^(0)-TDeltaS^(0)=-RTlnK and lnK=-((DeltaH^(0)-TDeltaS^(0))/(RT))`
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise MCQ HOTSPOT (SINGLE CORRENT TYPE)|71 Videos
  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise VERY SHORT TYPE QUESTIONS|53 Videos
  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise HIGHER ORDER THINKING SKILLS (HOTS) QUESTIONS|20 Videos
  • CHEMICAL KINETICS

    CHHAYA PUBLICATION|Exercise EXERCISE (NUMERICAL PROBLEMS)|37 Videos
  • CHEMISTRY IN EVERYDAY LIFE

    CHHAYA PUBLICATION|Exercise PRACTICE SET 15|15 Videos
CHHAYA PUBLICATION-CHEMICAL THERMODYNAMICS-ENTRANCE QUESTION BANK
  1. The heat of neutralisation of a strong base and a strong acid is 13.7 ...

    Text Solution

    |

  2. The entropy change involved in the isothermal reversible expansion of ...

    Text Solution

    |

  3. Among the following expressions which one is incorrect-

    Text Solution

    |

  4. A cylinder filled with 0.04 mol of ideal gas expands reversible from 5...

    Text Solution

    |

  5. For complete combustion of enthanol, C(2)H(5)OH(l)+3O(2)(g)to2CO(2)(...

    Text Solution

    |

  6. The following reaction is performed free energy of formation of NO(g) ...

    Text Solution

    |

  7. The standard Gibbs energy change at 300K for the reaction 2A hArr B+C ...

    Text Solution

    |

  8. The heats of combustion of carbon and carbon monoxide are -393.5 and -...

    Text Solution

    |

  9. Given, C(graphite)+O(2)(g)toCO(2)(g),Delta(r)H^(0)=-393.5kJ*mol^(-1) ...

    Text Solution

    |

  10. The combustion of benzene (l) gives CO(2)(g) and H(2)O(l). Given that ...

    Text Solution

    |

  11. If (1)/(2)AtoB,DeltaH=+150kJ*mol^(-1),3B to 2C+D,DeltaH=-125kJ*mol^(-1...

    Text Solution

    |

  12. Which is correct option for free expansion of an ideal gas under adiab...

    Text Solution

    |

  13. Enthalpy change for the reaction, 4H(g) to 2H(2)(g) is -869.5kJ. The d...

    Text Solution

    |

  14. If the enthalpy change for the transition of liquid water to steam is ...

    Text Solution

    |

  15. In which of the given reactions, standard reaction entropy change (Del...

    Text Solution

    |

  16. For the reaction, X(2)O(4)(l)to2XO(2)(g),DeltaU=2.1 kcal, DeltaS=20cal...

    Text Solution

    |

  17. Heat of combustion of carbon to CO(2) is -393.5 kJ/mol. The heat relea...

    Text Solution

    |

  18. For a sample of perfect gas when the pressure is changed isothermally ...

    Text Solution

    |

  19. Consider the following liquid-vapour equilibrium. liquid hArr vapour...

    Text Solution

    |

  20. The correct thermodynamic conditios for the spontaneous reaction at al...

    Text Solution

    |