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Calculate the concentrations of Ca^(2+) ...

Calculate the concentrations of `Ca^(2+)` and `PO_4^(3-)` ions in a saturated `[Ca_3(PO_4)_2]` solution. Given:
`K_(sp)[Ca_3(PO_4)_2]=2.0xx10^(-29)` (at `25^(@)C`)

Text Solution

Verified by Experts

`Ca_3(PO_4)_2(s) `K_(sp)=(3s)^3xx(2s)^2`
[S= solubility of `Ca_3(PO_4)_2]=108s^5`
or `108s^5=2xx10^(-29):.S=7.137xx10^(-7)(M)`
`:.[Ca^(2+)]=2S=3xx7.137xx10^(-7)=2.14xx10^(-6)(M)`
`[PO_4^(3-)]=2S=2xx7.137xx10^(-7)(M)=1.42xx10^(-6)(M)`
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