Home
Class 12
CHEMISTRY
Do you think the hydrides of N, O and F ...

Do you think the hydrides of N, O and F will have lower boiling points than hydrides of their corresponding group members? State reasons.

Text Solution

Verified by Experts

The hydrides of the elements N, O and F are `NH_(3), H_(2)O` and HF respectively. These hydrides are expected to have lower boiling points than that of their corresponding group members (`PH_(3), H_(2)S` & HCl) when their masses are considered.
However, because of high electronegativity of N, O and F, their hydrides undergo extensive hydrogen bonding (intermolecular). As a result, boiling points of `NH_(3), H_(2)O` and HF and much higher than the hydrides of their corresponding group members, i.e., `PH_(3), H_(2)S` and HCl respectively.
Promotional Banner

Topper's Solved these Questions

  • HYDROGEN

    CHHAYA PUBLICATION|Exercise SOLVED WBCHSE SCANNER|10 Videos
  • HYDROGEN

    CHHAYA PUBLICATION|Exercise SOLVED NCERT EXERCISE|48 Videos
  • HYDROGEN

    CHHAYA PUBLICATION|Exercise QUESTION-ANSWER ZONE FOR BOARD EXAMINATION (VERY SHORT ANSWER TYPE)|30 Videos
  • HYDROCARBONS

    CHHAYA PUBLICATION|Exercise PRACTICE SET 13|16 Videos
  • MODEL QUESTION PAPER

    CHHAYA PUBLICATION|Exercise Answer the following question (set-3)|130 Videos

Similar Questions

Explore conceptually related problems

Among the hydrides of Gr-15 elements, which have the lowest boiling point?

Which one of group -15 hydrides is the stronger boiling points?

Why are the group-2 metals harder and have higher melting and boiling points than group-I metals?

Which compound in each of the pairs have higher boiling point. Give reason. n-butyl chloride and isobutyl chloride

Explain why the freezing point, boiling point, heat of fusion and heat of vaporisation of water are higher as compared to the hydrides of the other members of same group (16).

How would you account for the following: The boiling points of ethers are much lower than those of the alcohols of comparable molar mass.

Assertion: Alcohols have higher boiling points than ethers of comparable molecular masses. Reason: Alcohols and ethers are isomerism in nature.

Which of the group-15 hydrides has the (1) highest thermal stability , (2) lowest boiling point,(3) highest reducing strenght (4) highest basic strength ?

CHHAYA PUBLICATION-HYDROGEN-SHORT ANSWER TYPE
  1. Write the reactions for: preparation of D(2)O(2) from potassium persu...

    Text Solution

    |

  2. Between deionised water and distilled water which one is more pure and...

    Text Solution

    |

  3. Rain water is soft, but after passing over hills and mountains it gets...

    Text Solution

    |

  4. Why is Na(2)O(2) used for purifying air in submarines and in crowded ...

    Text Solution

    |

  5. Comment on the reactions of dihydrogen with Chlorine

    Text Solution

    |

  6. Comment on the reactions of dihydrogen with sodium

    Text Solution

    |

  7. Comment on the reactions of dihydrogen with copper (II) oxide.

    Text Solution

    |

  8. An ionic alkali metal hydride has covalent character to some extent an...

    Text Solution

    |

  9. Sodium reacts with dihydrogen to form a crystalline ionic solid. It is...

    Text Solution

    |

  10. Why is sea water not used in boilers?

    Text Solution

    |

  11. The values of melting point, enthalpy of vaporisation and viscosity of...

    Text Solution

    |

  12. How will you prepare heavy water from ordinary water? Explain its prin...

    Text Solution

    |

  13. Can phosphorus form PH(5) with its outer electronic configuration of 3...

    Text Solution

    |

  14. How will you prepare dihydrogen from HNO(3) ?

    Text Solution

    |

  15. Do you think the hydrides of N, O and F will have lower boiling points...

    Text Solution

    |

  16. KF reacts with HF to form the compound, KF-2HF. Discuss the probable s...

    Text Solution

    |

  17. Calculate the amount of energy liberated due to combustion of 4g dihyd...

    Text Solution

    |

  18. Under what conditions, water reacts with calcium cyanamide and what ar...

    Text Solution

    |

  19. Discuss the industrial preparation of H(2)O(2) from 2ethylanthraquinol...

    Text Solution

    |

  20. Why H(2)O(2) is a better oxidant than water?

    Text Solution

    |