Home
Class 12
CHEMISTRY
Lambda(m)^(@) of NaCl, HCl and CH(3)COON...

`Lambda_(m)^(@)` of NaCl, HCl and `CH_(3)COONa` are 126.4, 425.9 and `"91.0 S.cm"^(2)."mol"^(-1)` respectively. `Lambda_(m)^(@)` for `CH_(3)COOH` will be -

A

`"180.5 S.cm"^(2)."mol"^(-1)`

B

`"290.8 S.cm"^(2)."mol"^(-1)`

C

`"390.5 S.cm"^(2)."mol"^(-1)`

D

`"425.5 S.cm"^(2)."mol"^(-1)`

Text Solution

Verified by Experts

The correct Answer is:
C

`Lambda_(m)^(@)(CH_(3)COOH)`
`=Lambda_(m)^(@)(CH_(3)COONa)+Lambda_(m)^(@)(HCl)-Lambda_(m)^(@)(NaCl)`
`=(91.0+425.9-126.4)=390.5" S.cm"^(2)."mol"^(-1)`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    CHHAYA PUBLICATION|Exercise ENTRANCE QUESTION BANK (AIIMS)|10 Videos
  • ELECTROCHEMISTRY

    CHHAYA PUBLICATION|Exercise SOLVED NCERT EXEMPLAR PROBLEMS (Multiple Choice Question)(Single Correct Type)|17 Videos
  • ELECTROCHEMISTRY

    CHHAYA PUBLICATION|Exercise ENTRANCE QUESTION BANK (JEE-MAIN)|10 Videos
  • D - AND F - BLOCK ELEMENTS

    CHHAYA PUBLICATION|Exercise PRACTICE SET 8 (Answer the following questions)|10 Videos
  • ENVIRONMENTAL CHEMISTRY

    CHHAYA PUBLICATION|Exercise PRACTICE SET 14(Answer the following questions)|6 Videos

Similar Questions

Explore conceptually related problems

Lambda_(m)^(@) for NaCl, HCl and NaAc are 126.4, 425.9 and "91 S.cm"^(2)."mol"^(-1) respectively. Calculate Lambda^(@) for Hac.

At infinite dilution, molar conductivities of HCl, NaCl and CH_(3)COONa solution are 426.2, 126.5 and 91.0 " ohm"^(-1)."cm"^(2)."mol"^(-1) respectively. On the basic of these values, determine the molar conductivity of CH_(3)COOH solution at infinite dilution.

At 25^(@) C, at infinite dilution, the molar conductivity of HCl, NaCl and CH_3COONa are 426.2, 126.5 and 91.0 ohm^(1)cm^2mol^(-1) respectively. Calculate molar conductivity of CH_3COOH at infinite dilution.

The values of Lambda_(m)^(@) for the aqueous solution of KCl and KNO_(3) are 149.86ohm^(-1)"cm"^(2)mol^(-1) and 145 ohm^(-1)cm^(2)mol^(-1) , respectively. If lambda_(m)^(@)(Cl^(-)) is "76.44 ohm"^(-1)."cm"^(2)."mol"^(-1) then lambda_(m)^(@)(NO_3^(-)) will be?

Write down Kohlrausch's law of independent migration of ions. Find out the molar conductivity of ammonium hydroxide at infinite dilution (Lambda_(m)^(@)) at 298K, given that (Lambda_(m)^(@)) values for NH_(4)Cl, NaCl and NaOH are 149, 126 and "248 S.cm"^(2)."mol"^(-1) respectively at 298 K.

The value of Lambda^(@) of ClCH_(2)COONa, NaCl and HCl solutions are 224, 38.2 and "203 ohm"^(-1)."cm."^(2)g-equiv"^(-1) respectively. Calculate the value of Lambda^(@) of aqueous solution of ClCH_(2)COOH .

The molar ionic conductances of Al(3+) and SO_(5)^(2-) ions in an infinitely dilute solution of Al_(2)(SO_(4))_(3) are 189 and "160 ohm"^(-1)."cm"^(2)."mol"^(-1), respectively. Determine Lambda^(@) and Lambda_(m)^(@) of Al_(2)(SO_(4))_(3) solution.

The equivalent conductances at infinite dilution of HCl, CH_(3)COONa and NaCl are "426.16, 91.0 and 126.45 ohm"^(-1) cm^(2)" gm.equivalent"^(-1) respectively.. Calculate the lambda_(oo) of acetic acid.

Lambda_(m)^(@)(NaCl)-Lambda_(m)^(@)(NaNO_(3))="3.7 ohm"^(-1)."cm"^(2)."mol"^(-1) . Find the value of Lambda_(LiCl)^(@)-Lambda_(LiNO_(3))^(@) .

At 26^(@)C, Lambda_(m)^(@)(NH_(4)Cl)="129.8 ohm"^(-1)."cm"^(2)."mol"^(-1) and Lambda_(m)^(@)(NaCl)="126.5 ohm"^(-1)."cm"^(2)."mol"^(-1) . Apart from the values of Lambda_(m)^(@)(NH_(4)Cl) and Lambda_(m)^(@)(NaCl) , which of the following quantities should be known, to determine the value of Lambda_(m)^(@)(NH_(4)OH)-

CHHAYA PUBLICATION-ELECTROCHEMISTRY-ENTRANCE QUESTION BANK (NEET)
  1. The electrode potential for Cu^(2+)(aq)+e rarr Cu^(+)(aq) and Cu^(+)(a...

    Text Solution

    |

  2. Limiting molar conductivity of NH(4)OH [i.e., Lambda(m)^(@)(NH(4)OH)] ...

    Text Solution

    |

  3. For successive members of the first series of the transition metals ar...

    Text Solution

    |

  4. Standard reduction potentials of the half reactions are given below : ...

    Text Solution

    |

  5. Lambda(m)^(@) of NaCl, HCl and CH(3)COONa are 126.4, 425.9 and "91.0 S...

    Text Solution

    |

  6. The Gibbs energy for the decomposition of Al(2)O(3) at 500^(@)C is as ...

    Text Solution

    |

  7. A button cell used in watches functions as following : Zn(s)+Ag(2)O(...

    Text Solution

    |

  8. A hydrogen gas electrode is made by dipping platinum wire in a solutio...

    Text Solution

    |

  9. At 25^(@)C molar conductivity of 0.1 molar aqueous of ammonium hydroxi...

    Text Solution

    |

  10. Weight of Ag (at wt. = 108) displaced by a quantity of electricity tha...

    Text Solution

    |

  11. When "0.1 mol "MnO(4)^(2-) is oxidised, quantity of electricity requir...

    Text Solution

    |

  12. A device that converts energy of combustion of fuels like hydrogen and...

    Text Solution

    |

  13. The pressure of H(2) required to make the potential of H(2) - electrod...

    Text Solution

    |

  14. The molar conductivity of a "0.5 mol.dm"^(3) solution of AgNO(3) with ...

    Text Solution

    |

  15. If the E("cell")^(@) for a given reaction has a negative value, which ...

    Text Solution

    |

  16. During the electrolysis of molten sodium chloride the time required to...

    Text Solution

    |

  17. The number of electron delivered at the cathode during electrolysis by...

    Text Solution

    |

  18. In the electrochemical cell: Zn|ZnSO(4)(0.01 M)||CuSO(4)(1.0M)|Cu ...

    Text Solution

    |

  19. Ionic mobility of which of the following alkali metal ions is lowest w...

    Text Solution

    |

  20. Consider the change in oxidation state of bromine corresponding to dif...

    Text Solution

    |