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Given : H^(+)(aq, 1M)+e rarr(1)/(2)H(2)(...

Given : `H^(+)(aq, 1M)+e rarr(1)/(2)H_(2)("g, 1atm"), E^(@)=0.00V Hg_(2)Cl_(2)(s)+2e rarr Hg(l) +2Cl^(-)(aq, 1M), E^(@)=+0.27V` In which of following galvanic cell, the given reaction occurs -
`H_(2)"(g, 1atm)"+Hg_(2)Cl_(2)(s)rarr 2Hg(l)+2H^(+)(1M)+2Cl^(-)(1M)`

A

`Hg|Hg_(2)Cl_(2)(s)|Cl^(-)(1M)||H^(+)(1M)H_(2)("g, 1atm")|Pt`

B

`Hg|Hg_(2)Cl_(2)(s)||H^(+)(1M)|H_(2)("g, 1atm")|Pt`

C

`Pt|H_(2)("g, 1 atm")|H^(+)(1M)||H_(2)Cl_(2)(s)|Hg`

D

`Pt|H_(2)("g, 1atm")H^(+)(1M)||Cl^(-)(1M)|Hg_(2)Cl_(2)(s)|Hg`

Text Solution

Verified by Experts

The correct Answer is:
D
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