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Find the stronger oxidising agent in eac...

Find the stronger oxidising agent in each pair, stating reason.
(d) `Cr^(3+), Fe^(3+)`
`"Given : "E_((1)/(2)Cl_(2)|Cl^(-))^(@)=+1.36V, E_((1)/(2)Br_(2)|Br^(-))^(@)=+1.07V,`
`E_(Cu^(2+)|Cu)^(@)=+0.34V, E_(Ag^(+)|Ag)^(@)=+0.80V,`
`E_(Pb^(2+)|Pb)^(@)=-0.13V, E_(Fe^(2+)|Fe)^(@)=-0.44V`,
`E_(Fe^(3+)|Fe)^(@)=-0.036V, E_(Cr^(3+)|Cr)^(@)=-0.74V`

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Find the stronger oxidising agent in each pair, stating reason. (a) Cl_(2), Br_(2) "Given : "E_((1)/(2)Cl_(2)|Cl^(-))^(@)=+1.36V, E_((1)/(2)Br_(2)|Br^(-))^(@)=+1.07V, E_(Cu^(2+)|Cu)^(@)=+0.34V, E_(Ag^(+)|Ag)^(@)=+0.80V, E_(Pb^(2+)|Pb)^(@)=-0.13V, E_(Fe^(2+)|Fe)^(@)=-0.44V , E_(Fe^(3+)|Fe)^(@)=-0.036V, E_(Cr^(3+)|Cr)^(@)=-0.74V

Find the stronger oxidising agent in each pair, stating reason. (c) Ag^(+), Cu^(2+) "Given : "E_((1)/(2)Cl_(2)|Cl^(-))^(@)=+1.36V, E_((1)/(2)Br_(2)|Br^(-))^(@)=+1.07V, E_(Cu^(2+)|Cu)^(@)=+0.34V, E_(Ag^(+)|Ag)^(@)=+0.80V, E_(Pb^(2+)|Pb)^(@)=-0.13V, E_(Fe^(2+)|Fe)^(@)=-0.44V , E_(Fe^(3+)|Fe)^(@)=-0.036V, E_(Cr^(3+)|Cr)^(@)=-0.74V

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Fe has a much lower tendency to get oxidised than Mn and Cr - explain. [Given : E_(Cr^(2+)|Cr)^(0)=-0.9V, E_(Cr^(3+)|Cr^(2+))^(0)=-0.4V E_(Mn^(2+)|Mn)^(0)=-1.2V, E_(Mn^(3+)|Mn^(2+))^(0)=+1.5V E_(Fe^(2+)|Fe)^(0)=-0.4V, E_(Fe^(3+)|Fe^(2+))^(0)=+0.8V ]

Stability of Fe^(3+) ion is greater than Mn^(3+) ion but less than Cr^(3+) - explain. [Given : E_(Cr^(2+)|Cr)^(0)=-0.9V, E_(Cr^(3+)|Cr^(2+))^(0)=-0.4V E_(Mn^(2+)|Mn)^(0)=-1.2V, E_(Mn^(3+)|Mn^(2+))^(0)=+1.5V E_(Fe^(2+)|Fe)^(0)=-0.4V, E_(Fe^(3+)|Fe^(2+))^(0)=+0.8V ]

Are the following reactions spontaneous? (a) Fe+Mg^(2+)rarr Fe^(2+)+Mg "Given : "E_(Fe^(2+)|Fe)^(@)=-0.44V, E_(Mg^(2+)|Mg)^(@)=-2.37V, E_(Cd^(2+)|Cd)^(@)=-0.40V, E_((1)/(2)Cl_(2)|Cl^(-))^(@)=+1.36V

Find the equilibrium constant for the reaction: Cu^(2+)+In^(2+)hArr Cu^(+)+In^(3+) Given : E_(Cu^(2+)|Cu^(+))^(@)=0.15V, E_(In^(2+)|In^(+))^(@)=-0.4V, E_(In^(3+)|In^(+))^(@)=-0.42V

Given that, E_(Zn^(2+)|Zn)^(@)=-0.76V, E_(Cu^(2+)|Cu)^(@)=+0.34V , E_(Ni^(2+)|Ni)^(@)=-0.25V and E_(Ag^(+)|Ag)^(@)=+0.80V Which metal ions are reduced by Ag^(+) ?

Are the following reactions spontaneous? (b) Cd+Cl_(2)rarr Cd^(2+)+2Cl^(-) "Given : "E_(Fe^(2+)|Fe)^(@)=-0.44V, E_(Mg^(2+)|Mg)^(@)=-2.37V, E_(Cd^(2+)|Cd)^(@)=-0.40V, E_((1)/(2)Cl_(2)|Cl^(-))^(@)=+1.36V

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