Home
Class 12
CHEMISTRY
Sucrose decomposes in acid solution into...

Sucrose decomposes in acid solution into glucose and fructose according to the first order rate law , with `t_(1//2)=3.00h` . What fraction of sample of sucrose remains after 8 hours ?

Text Solution

Verified by Experts

Decomposition of sucrose to glucose and fructose is a first order reaction.
`thereforek=(2.303)/(t)log.([A]_(0))/([A])`
At `t_(1//2)= 3 "hrs",k=(0.693)/(t_(1//2))=(0.693)/(3)=0.231h^(-1)`
`therefore0.231=(2.303)/(8)log.([A]_(0))/([A])`
or, `log.([A]_(0))/([A])=0.8024 " or, "([A]_(0))/([A])=6.345`
or, `([A]_(0))/([A])=(1)/(6.345)=0.158`
`therefore` The fraction that remains after 8 hours = 0.158
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    CHHAYA PUBLICATION|Exercise HIGHER ORDER THINKING SKILL (HOTS) QUESTIONS|18 Videos
  • CHEMICAL KINETICS

    CHHAYA PUBLICATION|Exercise ADVANCED LEVEL NUMERICAL BANK|16 Videos
  • CHEMICAL KINETICS

    CHHAYA PUBLICATION|Exercise SOLVED NCERT TEXTBOOK PROBLEMS (NCERT INTEXT QUESTIONS)|21 Videos
  • BIOMOLECULES

    CHHAYA PUBLICATION|Exercise Practic Set 29|1 Videos
  • CHEMICAL THERMODYNAMICS

    CHHAYA PUBLICATION|Exercise Practice Set 6|15 Videos

Similar Questions

Explore conceptually related problems

Sucrose decomposes in acid solution into glucose and fructose according to the first order rate law with t _1/2 = 3.00 hours. What fraction of the sample of sucrose remains after 8 hours?

The half -life of a first order reaction ArarrB is 10 min . What fraction of the reactant will be left behind after 1 h ?

In a first order reaction , the amount of reactant decomposed in the first 1 min is 1 % of its initial amount. What percent of the reactant will remain undecomposed after 1 hour from the start of the reaction ?

What is meant by pseudo unimolecular reaction? Explain with an example. 0.0625 g remains from 1 g of a radioactive element after 20 years of radioctive decay. Determine the rate constant and half-life (t_(1//2) of the reaction. How much of the element did remain after 10 years from the start?

What is meant by pseudo unimolecular reaction. Explain with an example. 0.0625g remains from 1g of a radioactive element after 20 years of radioactive decay. Determine the rate constant and half-line (t1/2) of the reaction. How much of the element did remain after 10 years from the start.

Calculate the rate constant and time required to complete 90% reaction for a first order reaction having t_(1/2) = 30 minutes. Find t_(1/2) for a 2nd order reaction K = 4.3xx10^-4 mol^-1 lit sec^-1 and initial conc. 0.24 (M).

The decomposition of a compound follows the rate law of a first order reaction. For the initial concentration of the compound to drop to (1)/(8) and (1)/(10) th of this value , times required are t_(1//8)th and t_(1//10) respectively. Find the value of (t_(1//8)/(t_(1//10))xx10). ["given":log"10^(2)=0.3]

Chromium metal can be plated out from an acidic solution containing CrO_(3) according to the following equation: CrO_(3)(aq)+6H^(+)(aq)+6e rarr Cr(s)+3H_(2)O (1) How many grams of chromium will be plated out by 24000C?

The rate constant of a first order reaction follows the equation logk(s^(-1))=22.3-(12.16xx10^(3))/(T)K At what temperature will the half-life of the reaction be 115.5 min ?

CHHAYA PUBLICATION-CHEMICAL KINETICS-SOLVED NCERT TEXTBOOK PROBLEMS (NCERT EXERCISE QUESTIONS)
  1. The experimental data for decomposition of N(2)O(2) [2N(2)O(5)rarr4NO(...

    Text Solution

    |

  2. The experimental data for decomposition of N(2)O(2) [2N(2)O(5)rarr4NO(...

    Text Solution

    |

  3. The experimental data for decomposition of N(2)O(2) [2N(2)O(5)rarr4NO(...

    Text Solution

    |

  4. The experimental data for decomposition of N(2)O(2) [2N(2)O(5)rarr4NO(...

    Text Solution

    |

  5. The experimental data for decomposition of N(2)O(2) [2N(2)O(5)rarr4NO(...

    Text Solution

    |

  6. The rate constant for a first order reaction is 60s^(-1) How much time...

    Text Solution

    |

  7. During nuclear explosion, one of the products is .^(90)"Sr" with half...

    Text Solution

    |

  8. For a first order reaction , show that time required for 99% completio...

    Text Solution

    |

  9. A first order reaction takes 40 min for 30% decomposition . Calculate ...

    Text Solution

    |

  10. For the decomposition of azoisopropane to hexane and nitrogen at 543 K...

    Text Solution

    |

  11. The following data were obtained during the first thermal decompositio...

    Text Solution

    |

  12. The rate constant for the decomposition of N(2)O(5) at various tempera...

    Text Solution

    |

  13. The rate constant for the decomposition of hydrocarbons is 2.418xx10^(...

    Text Solution

    |

  14. Consider a certain reaction Ararr products with k=2.0xx10^(-2)s^(-1) ...

    Text Solution

    |

  15. Sucrose decomposes in acid solution into glucose and fructose accordin...

    Text Solution

    |

  16. The decomposition of hydrocarbon follows the equation k =(4.5xx10^(1...

    Text Solution

    |

  17. The rate constant for the first order decomposition of H(2)O(2) is gi...

    Text Solution

    |

  18. The decomposition of A into product has value of k as 4.5xx10^(3)s^(-...

    Text Solution

    |

  19. The time required for 10% completion of a first order reaction at 298K...

    Text Solution

    |

  20. The rate of a reaction quadruples when the temperature changes from 2...

    Text Solution

    |