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Bond angle in PH(4)^(+) is higher than t...

Bond angle in `PH_(4)^(+)` is higher than that in `PH_(3)`. Why?

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P is `sp^(3)` -hybridised both in `PH_(3)` and `PH_(4)^(+)cdot PH_(4)^(+)` contains all four bond pairs with bond angle `109^(@)28'` , as expected in case of tetrahedral geometry. However, `PH_(3)` contains three bond pairs and one lone pair. Since lone pair-bond pair repulsion is greater than bond pair-bond pair repulsion, the bond angle reduces to `93.6^(@)` from `109^(@)28'`. Hence, the bond angle in `PH_(4)^(+)` is higher than `PH_(3)`.
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CHHAYA PUBLICATION-P-BLOCK ELEMENTS-SOLVED NCERT TEXTBOOK PROBLEMS
  1. What is the covalence of nitrogen in N(2)O(5) ?

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  2. In what way can it be proved that PH(3) is basic in nature?

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  3. Bond angle in PH(4)^(+) is higher than that in PH(3). Why?

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  4. What happens when white phosphorus is heated with concentrated NaOH so...

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  5. Why does PCl(3) fume in moisture?

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  6. Are all the five bonds in PCl(5) molecule equivalent? Justify your ans...

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  7. What happens when PCl(5) is heated?

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  8. Write a balanced equation for the hydrolytic reaction of PCl(5) in hea...

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  9. How do you account for the reducing behaviour of H(3)PO(2) on the basi...

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  10. What is the basicity of H(3)PO(4) ?

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  11. What happens when H(3)PO(3) is heated?

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  12. Elements of group-16 generally show lower value of first ionisation en...

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  13. H(2)S less acidic than H(2)Te. Why?

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  14. List the important sources of sulphur.

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  15. Write the order of thermal stability of the hydrides of group-16 eleme...

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  16. Why is H(2)O a liquid and H(2)S a gas?

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  17. Which of the following does not react with oxygen directly? Zn, Ti, Pt...

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  18. Complete the following reactions: C(2)H(4)+O(2)to

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  19. Complete the following reactions: 4Al+3O(2)to

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  20. Why does O(3) act as a powerful oxidising agent?

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