Home
Class 12
CHEMISTRY
Nitrogen exists as diatomic molecule and...

Nitrogen exists as diatomic molecule and phosphorus as `P_(4)`. Why?

Text Solution

Verified by Experts

Nitrogen forms `ppi-ppi` multiple bonds owing to its small size and high electronegativity.
Therefore it exists as a diatomic molecule, with a triple bond between two nitrogen atoms. However, the larger size and low electronegativity of P-atom does not promote the `ppi-ppi` multiple bonds between the P-atoms. Instead, it forms P-P single bonds and exists as tetra-atomic `(P_(4))` molecule.
Promotional Banner

Topper's Solved these Questions

  • P-BLOCK ELEMENTS

    CHHAYA PUBLICATION|Exercise HIGHER ORDER THINKING SKILL (HOTS) QUESTIONS|66 Videos
  • P-BLOCK ELEMENTS

    CHHAYA PUBLICATION|Exercise ENTRANCE QUESTION BANK|28 Videos
  • P-BLOCK ELEMENTS

    CHHAYA PUBLICATION|Exercise SOLVED NCERT TEXTBOOK PROBLEMS|58 Videos
  • ORGANIC CHEMISTRY : BASIC PRINCIPLES AND TECHNIQUES

    CHHAYA PUBLICATION|Exercise WARM UP EXERICSE|132 Videos
  • POLYMERS

    CHHAYA PUBLICATION|Exercise SOVLED CBSE SCANNER|18 Videos

Similar Questions

Explore conceptually related problems

Why do halogens exist as diatomic molecules ?

Write two examples of diatomic molecules.

Bond polarity of diatomic molecule is because of

Explain the following: Nitrogen is much less reactive than phosphorus.

Nitrogen is a gas while phosphorus is a solid-why?

How do the atoms exists in molecules?

H_(2)O molecule is a triatomic molecule but its geometry is not linear. Why ?

Glycosidic bonds exist in DNA molecule between (a) Sugar and phosphate (b) Any two nitrogen bases (c) Sugar and nitrogen base (d) Purines and pyrimidines

Why oxygen only forms diatomic molecule among group 16 elements and others form octa atomic solid?

Main axos of a diatomic molecule is Z orbitals P_x and P_y of two atoms overlap to form which of the following orbitals?

CHHAYA PUBLICATION-P-BLOCK ELEMENTS-NCERT EXERCISE QUESTIONS
  1. Why does R(3)P =O exist but R(3)N =O does not (R = alkyl group)?

    Text Solution

    |

  2. Explain: NH(3) is basic while BiH(3) is only feebly basic.

    Text Solution

    |

  3. Nitrogen exists as diatomic molecule and phosphorus as P(4). Why?

    Text Solution

    |

  4. Write main differences between the properties of white phosphorus and ...

    Text Solution

    |

  5. Why does nitrogen show catenation properties less than phosphorus?

    Text Solution

    |

  6. Give the disproportionation reaction of H(3)PO(3).

    Text Solution

    |

  7. Can PCl(5) act as an oxidising as well as a reducing agent? Justify.

    Text Solution

    |

  8. Justify the placement of O, S, Se, Te and Po in the same group of the ...

    Text Solution

    |

  9. Why is dioxygen a gas but sulphur a solid?

    Text Solution

    |

  10. Knowing the electron gain enthalpy values for O to O^(-) and OtoO^(2-)...

    Text Solution

    |

  11. Which aerosols deplete ozone?

    Text Solution

    |

  12. Describe manufacture of H(2)SO(4) by contact process.

    Text Solution

    |

  13. How is SO(2) an air pollutant?

    Text Solution

    |

  14. Why are halogens strong oxidising agents?

    Text Solution

    |

  15. Explain why fluorine forms only one oxoacid, HOF.

    Text Solution

    |

  16. Explain why inspite of nearly the same electronegativity, oxygen forms...

    Text Solution

    |

  17. Write two uses of ClO(2).

    Text Solution

    |

  18. Why are halogens coloured?

    Text Solution

    |

  19. Write the reactions of F(2) and Cl(2) with water.

    Text Solution

    |

  20. How can you prepare Cl(2) from HCl and HCl from Cl(2)? Write reactions...

    Text Solution

    |