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What is meant by 'disproportionation' of...

What is meant by 'disproportionation' of an oxidation state ? Give an example.

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When a particular oxidation state of an element becomes less stable relative to other oxidation states (one lower and one higher) of the same element, then the element in the given oxidation state undergoes simultaneous oxidation and reduction to form two different species containing lower and higher oxidation states of the element. This is called disproportionation of an oxidation state. For example, Cu(I) - compounds are unstable in aqueous solution and undergo disproportionation to form metallic copper Cu (0) and Cu (II) compound. `2Cu^(+)(aq)to Cu^(2+)(aq)+Cu(s)`
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CHHAYA PUBLICATION-D - AND F - BLOCK ELEMENTS -SOLVED NCERT TEXTBOOK PROBLEMS (NCERT INTEXT QUESTIONS)
  1. On what ground can you say that scandium (Z = 21) is a transition elem...

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  2. Why do the transition elements exhibit higher enthalpies of atomisatio...

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  3. Name a transition element which does not exhibit variable oxidation st...

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  4. Why is Cr^(2+) reducing and Mn^(3+) oxidising when both have d^(4) con...

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  5. How would you account for the increasing oxidising power in the series...

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  6. For the first row transition metals the E^(0) values are : |{:(E^(0)...

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  7. Why is the E^(0) value for the Mn^(3+)|Mn^(2+) couple much more positi...

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  8. Calculate the magnetic moment of a divalent ion in aqueoues solution i...

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  9. What is meant by 'disproportionation' of an oxidation state ? Give an ...

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  10. Name a member of the lanthanoid series which is well known to exhibit ...

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  11. Silver atom has completely filled d orbitals (4d^(10)) in its ground s...

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  12. In the series Sc (Z = 21) to Zn (Z = 30), enthalpy of atomisation of z...

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  13. Which of the 3d-series of the transition metals exhibits the largest n...

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  14. The E^(0)(M^(2+)|M) value for copper is positive (+0.34V). What is pos...

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  15. How would you account for the irregular variation of ionisation enthal...

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  16. Why is the highest oxidation state of a metal exhibited in its oxide o...

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  17. Which is a stronger reducing agent Cr^(2+) or Fe^(2+) & Why ?

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  18. Calculate the 'spin only' magnetic moment of M^(2+)(aq) ion (Z = 27).

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  19. Explain why Cu^(+) ion is not stable in aqueous solutions.

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  20. Actinoid contraction is greater from element to element than lanthanoi...

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