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For M^(2+)|M and M^(3+)|M^(2+) systems t...

For `M^(2+)|M` and `M^(3+)|M^(2+)` systems the `E^(0)` values for some metals are as follows :
`{:(Cr^(2+)"|"Cr,,-0.9V,,Cr^(3+)|Cr^(2+),,-0.4V),(Mn^(2+)"|"Mn,,-1.2V,,Mn^(3+)|Mn^(2+),,+1.5V),(Fe^(2+)"|"Fe,,-0.4V,,Fe^(3+)|Fe^(2+),,+0.8V):}`
Use this data to comment upon :
the stability of `Fe^(3+)` in acid solution as compared to that of `Cr^(3+)` or `Mn^(3+)`

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Verified by Experts

We know that, greater the reduction potential of a system `(M^(3+)|M^(2+))`, higher is the tendency its highest `(M^(3+))` to undergo reduction. Thus, `Mn^(3+)` with highest reduction potential would be most readily reduced to `Mn^(2+)` and hence, is least stable. The negative reduction potential of `Cr^(3+)|Cr^(2+)` system shows that `Cr^(3+)` ion has the least tendency to undergo reduction to `Cr^(2+)` , and hence, is most stable. So stability sequence is : `Mn^(3+)lt Fe^(3+)lt Cr^(3+)`.
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For M^(2+)|M and M^(3+)|M^(2+) systems the E^(0) values for some metals are as follows : {:(Cr^(2+)"|"Cr,,-0.9V,,Cr^(3+)|Cr^(2+),,-0.4V),(Mn^(2+)"|"Mn,,-1.2V,,Mn^(3+)|Mn^(2+),,+1.5V),(Fe^(2+)"|"Fe,,-0.4V,,Fe^(3+)|Fe^(2+),,+0.8V):} Use this data to comment upon : the ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.

Fe has a much lower tendency to get oxidised than Mn and Cr - explain. [Given : E_(Cr^(2+)|Cr)^(0)=-0.9V, E_(Cr^(3+)|Cr^(2+))^(0)=-0.4V E_(Mn^(2+)|Mn)^(0)=-1.2V, E_(Mn^(3+)|Mn^(2+))^(0)=+1.5V E_(Fe^(2+)|Fe)^(0)=-0.4V, E_(Fe^(3+)|Fe^(2+))^(0)=+0.8V ]

Stability of Fe^(3+) ion is greater than Mn^(3+) ion but less than Cr^(3+) - explain. [Given : E_(Cr^(2+)|Cr)^(0)=-0.9V, E_(Cr^(3+)|Cr^(2+))^(0)=-0.4V E_(Mn^(2+)|Mn)^(0)=-1.2V, E_(Mn^(3+)|Mn^(2+))^(0)=+1.5V E_(Fe^(2+)|Fe)^(0)=-0.4V, E_(Fe^(3+)|Fe^(2+))^(0)=+0.8V ]

E_(Cr^(3+)|Cr^(2+))^(0)=-0.4V, E_(Mn^(3+)|Mn^(2+))^(0)=+1.5V , E_(Fe^(3+)|Fe^(2+))^(0)=+0.8V , discuss the tendency of the bivalent ions to transform iont + 3 oxidation state on the basis of the above data.

Given : E_(Cr^(3+)|Cr)^(@)=-0.74V, E_(Fe^(3+)|Fe^(2+))^(@)=+0.77V . What happens when Cr is mixed with a solution of Fe(III) ion?

Fe^(2+) has a greater tendency to attain the + 3 oxidation state as compared to Mn^(2+) . Give reason.

For the four successive transition elements (Cr, Mn, Fe and Co), the stability of + 2 oxidation state will be in which of the following order -

Why is the E^(0) value for the Mn^(3+)|Mn^(2+) couple much more positive than that for Cr^(3+)|Cr^(2+) or Fe^(3+)|Fe^(2+) ? Explain.

Given : E_(Cr^(3+)|Cr)^(@)=-0.74V, E_(MnO_(4)^(-)|Mn^(2+))^(@)=1.51V E_(Cr_(2)O_(7)^(2-)|Cr^(3+))^(@)=1.33V, E_(Cl|Cl^(-))^(@)=1.36V Based on the data, strongest oxidising agent -

Calculate the number of d-electrons in the following ions : Ti^(2+), V^(2+), Cr^(3+), Mn^(2+), Fe^(2+), Fe^(3+), Co^(2+), Ni^(2+), Cu^(2+) .

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