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For M^(2+)|M and M^(3+)|M^(2+) systems t...

For `M^(2+)|M` and `M^(3+)|M^(2+)` systems the `E^(0)` values for some metals are as follows :
`{:(Cr^(2+)"|"Cr,,-0.9V,,Cr^(3+)|Cr^(2+),,-0.4V),(Mn^(2+)"|"Mn,,-1.2V,,Mn^(3+)|Mn^(2+),,+1.5V),(Fe^(2+)"|"Fe,,-0.4V,,Fe^(3+)|Fe^(2+),,+0.8V):}`
Use this data to comment upon :
the ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.

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Verified by Experts

Lower the reduction potential of a metal, greater is the ease with which it undergoes oxidation. Thus from the given values it can be predicted that Mn is most readily oxidised to `Mn^(2+)` and Fe is oxidised least readily to `Fe^(2+)`. Thus the tendency of the metals to undergo oxidation is : `Mn gt Cr gt Fe`.
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For M^(2+)|M and M^(3+)|M^(2+) systems the E^(0) values for some metals are as follows : {:(Cr^(2+)"|"Cr,,-0.9V,,Cr^(3+)|Cr^(2+),,-0.4V),(Mn^(2+)"|"Mn,,-1.2V,,Mn^(3+)|Mn^(2+),,+1.5V),(Fe^(2+)"|"Fe,,-0.4V,,Fe^(3+)|Fe^(2+),,+0.8V):} Use this data to comment upon : the stability of Fe^(3+) in acid solution as compared to that of Cr^(3+) or Mn^(3+)

Fe has a much lower tendency to get oxidised than Mn and Cr - explain. [Given : E_(Cr^(2+)|Cr)^(0)=-0.9V, E_(Cr^(3+)|Cr^(2+))^(0)=-0.4V E_(Mn^(2+)|Mn)^(0)=-1.2V, E_(Mn^(3+)|Mn^(2+))^(0)=+1.5V E_(Fe^(2+)|Fe)^(0)=-0.4V, E_(Fe^(3+)|Fe^(2+))^(0)=+0.8V ]

Stability of Fe^(3+) ion is greater than Mn^(3+) ion but less than Cr^(3+) - explain. [Given : E_(Cr^(2+)|Cr)^(0)=-0.9V, E_(Cr^(3+)|Cr^(2+))^(0)=-0.4V E_(Mn^(2+)|Mn)^(0)=-1.2V, E_(Mn^(3+)|Mn^(2+))^(0)=+1.5V E_(Fe^(2+)|Fe)^(0)=-0.4V, E_(Fe^(3+)|Fe^(2+))^(0)=+0.8V ]

E_(Cr^(3+)|Cr^(2+))^(0)=-0.4V, E_(Mn^(3+)|Mn^(2+))^(0)=+1.5V , E_(Fe^(3+)|Fe^(2+))^(0)=+0.8V , discuss the tendency of the bivalent ions to transform iont + 3 oxidation state on the basis of the above data.

Given : E_(Cr^(3+)|Cr)^(@)=-0.74V, E_(MnO_(4)^(-)|Mn^(2+))^(@)=1.51V E_(Cr_(2)O_(7)^(2-)|Cr^(3+))^(@)=1.33V, E_(Cl|Cl^(-))^(@)=1.36V Based on the data, strongest oxidising agent -

Given : E_(Cr^(3+)|Cr)^(@)=-0.74V, E_(Fe^(3+)|Fe^(2+))^(@)=+0.77V . What happens when Cr is mixed with a solution of Fe(III) ion?

Why is the E^(0) value for the Mn^(3+)|Mn^(2+) couple much more positive than that for Cr^(3+)|Cr^(2+) or Fe^(3+)|Fe^(2+) ? Explain.

Calculate the number of d-electrons in the following ions : Ti^(2+), V^(2+), Cr^(3+), Mn^(2+), Fe^(2+), Fe^(3+), Co^(2+), Ni^(2+), Cu^(2+) .

Calculate the emf of the following call at 298 K : 2Cr(s)+3Fe^(2+)(0.1M)rarr2Cr^(3+)(0.01M)+3Fe(s) ["Given : "E_((Cr^(3+)|Cr))^(@)=-0.74V, E_((Fe^(2+)|Fe))^(@)=-0.44V]

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