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When KMnO(4) solution is added to oxalic...

When `KMnO_(4)` solution is added to oxalic acid solution, the decolourisation is slow in the beginning but becomes instantaneous after some time because -

A

`CO_(2)` is formed as the product

B

reaction is exothermic

C

`MnO_(4)^(-)` catalyses the reaction

D

`Mn^(2+)` acts as autocatalyst

Text Solution

Verified by Experts

The correct Answer is:
D

Oxalic acid reduces `KMnO_(4)` to form `Mn^(2+)` ion, which acts as autocatalyst. `2MnO_(4)^(-)+5C_(2)O_(4)^(2-)+16H^(+)rarr 2Mn^(2+)+10CO_(2)+8H_(2)O`
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CHHAYA PUBLICATION-D - AND F - BLOCK ELEMENTS -SOLVED NCERT EXEMPLAR PROBLEMS (Multiple Choice Question)
  1. Which of the following oxidation states is common for all lanthanoids ...

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  2. Which of the following reactions are disproportionation reactions - ...

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  3. When KMnO(4) solution is added to oxalic acid solution, the decolouris...

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  4. There are 14 elements in actinoid series. Which of the following eleme...

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  5. KMnO(4) acts as an oxidising agent in acidic medium. The number of mol...

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  6. Which of the following is amphoteric oxide ? Mn(2)O(7), CrO(3), Cr(2)O...

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  7. Gadolinium belongs to 4f - series. It's atomic number is 64. Which of ...

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  8. Interstitial compounds are formed when small atoms are trapped inside ...

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  9. The magnetic moment is associated with its spin angular momentum and o...

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  10. KMnO(4) acts as an oxidising agent in alkaline medium. When alkaline K...

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  11. Which of the following statements is not correct -

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  12. When acidified K(2)Cr(2)O(7) solution is added to solution of Sn^(2+) ...

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  13. Highest oxidation state of manganese in fluoride is + 4 (MnF(4)) but h...

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  14. Although zirconium belongs to 4d transition series and hafnium to 5d t...

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  15. Why is HCl not used to make the medium acidic in oxidation reactions o...

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  16. Generally transition elements and their salts are coloured due to the ...

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  17. Transition elements show magnetic moment due to spin and orbital motio...

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  18. In the form of dichromate, Cr(VI) is a strong oxidising agent in acidi...

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  19. Which of the following actinoids show oxidation states upto + 7 -

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  20. General electronic configuration of actinoids is (n-2)f^(1-14)(n-1)d^(...

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