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Explain the following - (a) Melting poin...

Explain the following - (a) Melting point of Fe is higher than that of Cu. (b) Magnetic moment of `Ni^(2+)` is lower than that of `Co^(2+)`. (c ) Scandium does not produce coloured ions but still it is a transition element. (d) The increasing order of oxidation states of the oxo - ions is : `VO_(2)^(+)lt CrO_(7)^(2-)lt MnO_(4)^(-)`

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(a) N/A (b) N/A (c ) Sc ghas partially filled d - orbitals in its penultimate shell but `Sc^(3+)` has no d - electron and thus d - d transition is not possible (d) N/A
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CHHAYA PUBLICATION-D - AND F - BLOCK ELEMENTS -EXERCISE (SHORT ANSWER-TYPE QUESTIONS)
  1. What are transition elements ? Mention the characteristic properties o...

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  2. Explain the following - (a) Melting point of Fe is higher than that of...

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  3. E(Cr^(3+)|Cr^(2+))^(0)=-0.4V, E(Mn^(3+)|Mn^(2+))^(0)=+1.5V, E(Fe^(3+...

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  4. Cr is a solid metal while Hg is a liquid metal - give reasons.

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  5. Both transition elements and representative elements exhibit variable ...

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  6. The value of third ionisation enthalpy of manganese is much higher tha...

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  7. Transition elements have higher enthalpies of atomisation. Why ?

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  8. For first row transition metals, E^(0) values are irregular - explain.

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  9. Actinoids exhibit more oxidation states than lanthanoids. Why ?

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  10. To calculate the magnetic moment of lanthanoid ions, both spin angular...

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  11. Why are + 3 oxidation states of gadolinium and lutetium stable ?

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  12. The colour of complex compounds of d - block elements depends on the l...

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  13. Why is the value of magnetic moment of actinoids less than that of lan...

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  14. Discuss three dissimilarities between lanthanoids and actinoids.

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  15. Why are transition elements having d^(1) - configuration unstable ?

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  16. Discuss the characteristic properties of the transition elements with ...

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  17. How is K(2)Cr(2)O(7) prepared from chromite ore ? Give the reactions i...

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  18. Describe the process of KMnO(4) preparation from pyrolusite ore. Menti...

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  19. {:(,IE(1)+IE(2),IE(3)+IE(4)),("Element",(KJ.mol^(-1)),(KJ.mol^(-1))),(...

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  20. A blackish - brown solid (A) is oxidised in air with the hydroxide of ...

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