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E(Cr^(3+)|Cr^(2+))^(0)=-0.4V, E(Mn^(3+)|...

`E_(Cr^(3+)|Cr^(2+))^(0)=-0.4V, E_(Mn^(3+)|Mn^(2+))^(0)=+1.5V`,
`E_(Fe^(3+)|Fe^(2+))^(0)=+0.8V`, discuss the tendency of the bivalent ions to transform iont + 3 oxidation state on the basis of the above data.

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Given : E_(Cr^(3+)|Cr)^(@)=-0.74V, E_(MnO_(4)^(-)|Mn^(2+))^(@)=1.51V E_(Cr_(2)O_(7)^(2-)|Cr^(3+))^(@)=1.33V, E_(Cl|Cl^(-))^(@)=1.36V Based on the data, strongest oxidising agent -

Given : E_(Cr^(3+)|Cr)^(@)=-0.74V, E_(Fe^(3+)|Fe^(2+))^(@)=+0.77V . What happens when Cr is mixed with a solution of Fe(III) ion?

Fe^(2+) has a greater tendency to attain the + 3 oxidation state as compared to Mn^(2+) . Give reason.

Given E_(Cl_(2)|Cl^(-))^(0) = 1.36V, E_(Cr^(3+)|Cr)^(0) = -0.74V, E_(Cr_(2)O_(7)^(2-)|Cr^(3+))^(0) = 1.33V, E_(MnO_(4)^(-)|Mn^(2+))^(0) = 1.51 V. Among the following , the strongest reducing agent is -

Given that : E_(Ni^(2+)|Ni)^(@)=-0.25V, E_(Cd^(2+)|Cd)^(@)=-0.40V, e_(Fe^(2+)|Fe)^(@)=-0.44V, E_(Cu^(2+)|Cu)^(@)=+0.34V, E_(Fe^(3+)|Fe)^(@)=-0.036V, E_(2H^(+)|H_(2))^(@)=0.00V, E_(I_(2))|(2I^(-))^(@)=+0.80V Select appropriate species in each of the following cases : I^(-) is oxidised but not Br^(-) .

Use the given data E_(Cr_(2)O_(7)^(2-)|Cr^(3+))^(@)=+1.33V, E_(Cl_(2)|Cl^(-))^(@)=+1.36V E_(MnO_(4)^(-)|Mn^(2+))^(@)=+1.51V, E_(Cr^(3+)|Cr)^(@)=-0.74V find out in which option the order of reducing power is correct -

For M^(2+)|M and M^(3+)|M^(2+) systems the E^(0) values for some metals are as follows : {:(Cr^(2+)"|"Cr,,-0.9V,,Cr^(3+)|Cr^(2+),,-0.4V),(Mn^(2+)"|"Mn,,-1.2V,,Mn^(3+)|Mn^(2+),,+1.5V),(Fe^(2+)"|"Fe,,-0.4V,,Fe^(3+)|Fe^(2+),,+0.8V):} Use this data to comment upon : the stability of Fe^(3+) in acid solution as compared to that of Cr^(3+) or Mn^(3+)

For M^(2+)|M and M^(3+)|M^(2+) systems the E^(0) values for some metals are as follows : {:(Cr^(2+)"|"Cr,,-0.9V,,Cr^(3+)|Cr^(2+),,-0.4V),(Mn^(2+)"|"Mn,,-1.2V,,Mn^(3+)|Mn^(2+),,+1.5V),(Fe^(2+)"|"Fe,,-0.4V,,Fe^(3+)|Fe^(2+),,+0.8V):} Use this data to comment upon : the ease with which iron can be oxidised as compared to a similar process for either chromium or manganese metal.

Given : E_(Cl_(2)|Cl^(-))^(@)=1.36V, E_(Cr^(3+)|Cr)^(@)=-0.74V, E_(Cr_(2)O_(7)^(2-)|Cr^(3+))^(@)=1.33V, E_(MnO_(4)^(-)|Mn^(2+))^(@)=1.51V . Among the following the strongest reducing agent is -

CHHAYA PUBLICATION-D - AND F - BLOCK ELEMENTS -EXERCISE (SHORT ANSWER-TYPE QUESTIONS)
  1. What are transition elements ? Mention the characteristic properties o...

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  2. Explain the following - (a) Melting point of Fe is higher than that of...

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  3. E(Cr^(3+)|Cr^(2+))^(0)=-0.4V, E(Mn^(3+)|Mn^(2+))^(0)=+1.5V, E(Fe^(3+...

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  4. Cr is a solid metal while Hg is a liquid metal - give reasons.

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  5. Both transition elements and representative elements exhibit variable ...

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  6. The value of third ionisation enthalpy of manganese is much higher tha...

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  7. Transition elements have higher enthalpies of atomisation. Why ?

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  8. For first row transition metals, E^(0) values are irregular - explain.

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  9. Actinoids exhibit more oxidation states than lanthanoids. Why ?

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  10. To calculate the magnetic moment of lanthanoid ions, both spin angular...

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  11. Why are + 3 oxidation states of gadolinium and lutetium stable ?

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  12. The colour of complex compounds of d - block elements depends on the l...

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  13. Why is the value of magnetic moment of actinoids less than that of lan...

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  14. Discuss three dissimilarities between lanthanoids and actinoids.

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  15. Why are transition elements having d^(1) - configuration unstable ?

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  16. Discuss the characteristic properties of the transition elements with ...

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  17. How is K(2)Cr(2)O(7) prepared from chromite ore ? Give the reactions i...

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  18. Describe the process of KMnO(4) preparation from pyrolusite ore. Menti...

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  19. {:(,IE(1)+IE(2),IE(3)+IE(4)),("Element",(KJ.mol^(-1)),(KJ.mol^(-1))),(...

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  20. A blackish - brown solid (A) is oxidised in air with the hydroxide of ...

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