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The tetrahedral compounds of the type MA...

The tetrahedral compounds of the type `MA_(4), MA_(3)B, MA_(2)B_(2), MA_(2)BC`, do not exhibit geometrical isomerism - justify the statement (M = central metal atom or ion, A, B, C, D = monodenatate ligands).

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Why do the tetrahedral compounds of the type MA_(2)B_(2) not display geometrical isomerism?

The square planar complexes with coordination number 4 (MA_(2)B_(2) or MA_(2)BC) show geometrical isomerism but tetrahedral complexes do not. Explain.

What are facial and meridional isomers? Explain with the help of an MA_(3)B_(3) type compound with (A, B = monodenate ligands).

Which of the following exhibits geometrical isomerism? (1) linear (2) square planar (3) tetrahedral (4) octahedral

Calculate the oxidation number of the central metal atoms or ions : (any 4): (5) [Co(NH_(3))_(5)(ONO)]^(2+)

Calculate the oxidation number of the central metal atoms or ions : (any 4): (2) [PtClNO_(2)(NH_(3))_(4)]^(2+)

Calculate the oxidation number of the central metal atoms or ions : (any 4): (3) [Cr(C_(2)O_(4))_(3)]^(3-)

Calculate the oxidation number of the central metal atom or ion for the following : (i) [Cr(C_(2)O_(4))_(3)]^(3-)

Calculate the oxidation number of the central metal atom or ion for the following : (iii) [PtClNO_(2)(NH_(3))_(4)]^(2+) .

Give an example of a neutral coordination compound in which the central metal atom is sp^(3)d^(2) hybridised.

CHHAYA PUBLICATION-COORDINATION COMPOUNDS OR COMPLEX COMPOUNDS-WARM UP EXERCISE
  1. Identify the isomerism exhibited by the complexes, (i) [Co(NH(3))(5)(O...

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  2. Write the ionisation of [Co(NH(3))(5)SO(4)]Br. Why does the compound e...

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  3. The tetrahedral compounds of the type MA(4), MA(3)B, MA(2)B(2), MA(2)B...

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  4. What are facial and meridional isomers? Explain with the help of an MA...

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  5. Identify the type of isomerism in the following compounds : (i) [Co(...

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  6. Identify the type of isomerism in the following compounds : (ii) [Zn...

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  7. Write the formulas of the ionisation isomers of the following : (i) ...

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  8. Write the formulas of the ionisation isomers of the following : (ii)...

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  9. What do you mean by inner orbital and outer orbital complex?

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  10. How do you determine the hybridisation of the central metal ion of a c...

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  11. Discuss the formation of [Ni(NH(3))(4)]^(2+) with the help of valence ...

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  12. Discuss the formation of [FeF(6)]^(3-) with the help of valence bond t...

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  13. Write the limitations of valence bond theory.

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  14. Why do Co^(2+), Ni^(2+), Cu^(2+), Zn^(2+) always form outer orbital oc...

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  15. What is crystal field splitting? How do the d-orbitals split under the...

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  16. What do you mean by crystal field stabilisation energy (CFSE)? Calcula...

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  17. How d-orbitals undergo splitting in a tetrahedral crystal field?

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  18. What do you mean by spectrochemical series? Arrange the ligands of the...

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  19. Explain what happens when [Ti(H(2)O)(6)]Cl(3) is heated.

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  20. Why does the colour of aqueous NiCl(2) solution change at various stag...

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