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Out of H(3)C-underset(CH3)underset(|)(CH...

Out of `H_(3)C-underset(CH_3)underset(|)(CH)-CH_(2)Cl and H_(3)C-CH_(2)-underset(CH_3)underset(|)(C)HCl` which is more reactive towards `S_(N)1` reaction and why?

Text Solution

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`H_(3)C-CH_(2)-underset(CH_3)underset(|)(CH)-Cl` is more reactive towards `S_(N)1` reaction as it is a secondary halide and the other hand, `CH_(2)underset(CH_3)underset(|)(C)HCH_(2)Cl` is a halide and the `1^(@)` carbocation formed which is not so stable.
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