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To a solution of a substance, gradual ad...

To a solution of a substance, gradual addition of ammonium hydroxide results in a brownish black precipitate which does not dissolve in excess of `NH_(4)OH`. However, when KI (no in excess) is added to the original solution, a green precipitate is formed. The solution contained:

A

lead salt

B

silver salt

C

mercurous salt

D

copper salt

Text Solution

Verified by Experts

The correct Answer is:
C

`{:(Hg_(2)^(2+)overset(NH_(4)OH)rarrubrace(Hg+HgO.Hg(NH_(2))NO_(2))_("Black")darr),(darrKI),(underset(("Green ppt."))(Hg_(2)I_(2)darr)):}`
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GRB PUBLICATION-SALT ANALYSIS-G: Ist Group Cations
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