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L.C.A.O. principle is involved in the fo...

L.C.A.O. principle is involved in the formation of molecular orbitals according to molecular obtital theory. The energy of bonding molecular orbital is less than that of the combining atomic orbitals while that of the anitibonding bonding melecular orbital is more. The B.O. `=^(1//2)[N_(b)-N_(a)]`
Answer the following questions on the basis of the above paragraph :
(i) What is bonding molecular orbital ?
(ii) Calculate B.O. of `He_(2)` molecule.

Text Solution

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(i) A bonding molecule is formed by the Linear Combination of the wave functions (L.C.A.O.) of the combining atomic orbitals.
(ii) Molecular orbital electronic configuration of `He_(2)=[sigma_(1s)]^(2)[sigma_(1s)^(**)]^(2).`
`B.O.=^(1//2)[N_(b)-N_(a)]=^(1//2)[2-2]="zero".`
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According to molecular orbital theory,

According to Molecular Orbital Theory,

L.C.A.O. Principle is involved in the formationof the molecular orbitals according ot molecular orbital theory. The energy of the bonding molecular orbital is less than that of thecombining atomic orbitals while that of the antibonding molecular orbitals while that of the order (B.O.)=1/2(N_(b)-N_(a)) helps in predicting (i) formation of molecules/molecular ions, bond dossociation energy, stability and bond length. Only the molecules or ions with positive B.O. can be formed. These will be diamagnetic if all molecular orbitals are dilled and paramagnetic if one of more are half filled. The atomic prbitals at the time of overlap must have the same symmetry as well. The bond order (B.O.) in B_(2) molecule is:

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