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Statement 1: BF(3) moleculeis planar whi...

Statement 1: `BF_(3)` moleculeis planar while `NF_(3)` is pyramidal.
Statement 2: N atom is smalar in size as compared ot B atom.

A

Statement-1 is true, Statement-2 is also true, Statement -2 is the correct explanation of statement-1

B

Statement -1 is true , Statement 2 is also true, Statement-2 is not the correct explanation of Statement-1

C

Statement-1 is true, Statement-2 is false.

D

Statement-1 is false, Statement-2 is true.

Text Solution

Verified by Experts

The correct Answer is:
b

In `BF_(3),` the B atom has three shared electron pairs while in `NF_(5),` the N atom has five shared pairs of electrons.
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Assertion(A) - BF_3 molecule is planar but NF_3 is pyramidal Reason( R )-N atom is smaller than B

The BF_3 is a planar molecule where as NF_3 is pyramidal because :

Statement-1: NCl_(3) is hydrolysed by water by NF_(3) is not hydrolysed. Statement-2: N does not has vacant orbital for expansion of octet.

Statement-1 : Bond dissociation energy of F_(2) is more than Cl_(2) . Statement-2 : Due to smaller size of fluorine there are greater electron repulsions between the F atoms than Cl atoms.

Statement-1 BF_(3) is a weaker Lewis acid than BCl_(3) Statement -2: BF_(3) molecule is stabilized to a greater extent than BCl_(3) by p pi -p pi back bonding.

Assertion:- NO_(3)^(-) is planar while NH_(3) is pyramidal Reason:- N in NO_(3)^(-) is sp^(3) and in NH_(3) it is sp^(3) hybridised with one ione pair.

Statement-1: NH_(3) is more basic than NF_(3) Statement-2: F is more electronegative than H.

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