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Classify the following reactions in one ...

Classify the following reactions in one of the reaction type studied in this unit
(i) `CH_(3)CH_(2)Br+SH^(-) rarr CH_(3)CH_(2)SH+Br^(-)`
(ii) `(CH_(3))_(2)C=CH_(2)+HCl rarr (CH_(3))_(2)C(Cl)CH_(3)`
(iii) `(CH_(3))_(3)C CH_(2)OH+HBr rarr (CH_(3))_(2)CBrCH_(2)CH_(3)`
(iv) `CH_(3)CH_(2)Br+HO^(-) rarr CH_(2)=CH_(2)+H_(2)O+Br^(-)`

Text Solution

Verified by Experts

(i) Nucleophilic substitution
(ii) Electrophilic addition
(iii) Rearrangement of carbocation intermediate formed followed by nuclephilic substitution.
(iv) Elimination.
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Classify the following reactions in one of the reaction type studied in this unit. (a) CH_(3)CH_(2)Br+HS^(-)toCH_(3)CH_(2)SH+Br^(-) (b) (CH_(3))_(2)C=CH_(2)+HCl to(CH_(3))_(2)ClC-CH_(3) (c) CH_(3)CH_(2)Br+HO^(-)toCH_(2)=CH_(2)+H_(2)O+ Br^(-) (d) (CH_(3))_(3)C-CH_(2)OH+HBrto(CH_(3))_(2)CBrCH_(2)CH_(2)CH_(3)+H_(2)O

Classify the following in one of the reaction type studied. (a) CH_3CH_2Br + HS^(Ө) rarr CH_3CH_2SH + Br^(Ө) (b) (CH_3)_2C = CH_2 + HC1 rarr (CH_3)_2 C1C - CH_3 ( c) (CH_3)_3 C - CH_2OH + HBr rarr (CH_3)_2 CBr CH_2 CH_3 (d) CH_3CH_2 Br + HO^(Ө) rarr CH_2 = CH_2 .

Predict the order of reactivity of the following compounds in dehydrohalogenation: (a) CH_(3)CH_(2)CH_(2)CH_(2)Cl, (CH_(3))_(2)CHCH_(2)Cl, (CH_(3))_(2)CH-CH_(2)Br, CH_(3)CH(Br)CH_(2)CH_(3), (CH_(3))_(3)C-Br (b) CH_(3)CH(Br)CH_(3), CH_(3)CH_(2)CH_(2)Br, (CH_(3))_(2)CHCH_(2)Br, (CH_(3))_(3)C CH_(2)Br

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