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why is Fe0(s) not formed in stoichio...

why is ` Fe0(s)` not formed in stoichiometric compostion ?

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The chemical formula suggests a stoichiometric composition for the metal oxide )FeO). However, it is found to have compposition of `Fe_(0.95)O`. This means that Fe and O are not in stoichiometric proportions. In fact in the cystal lattice of ferrous oxide (FeO), some `Fe^(2+)` ions are missing and the loss of positive charge is made up by some `Fe^(3+)` ions. Since lesser number of `Fe^(3+)` ions are needed to maintain the electrical neutrality of the lattice, this shows that FeO is not formed in stoichiometric composition.
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Analyses shows that FeO has a non-stoichiometric composition with formula Fe_(0.95)O_(1.00) . Give reason.

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A sample of ferrous oxide has actual formula Fe_(0.93)O_(1..00) . In this sample what fraction of metal ions are Fe^(2+) ions? What type of non-stoichiometric defect is present in this sample ?

DINESH PUBLICATION-SOLID STATE-N.C.E.R.T
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