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Chloroformic acid does not exist while c...

Chloroformic acid does not exist while chloroethylformate exists. Explain.

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Strong-I effect due to Cl decarboxylates chloroformic acid. It therefore, does not exist

Strong-I effect of Cl is very much neutralised by +I effect of ethoxy group and decarboxylation does not take place in chloroethylformate ester (No decarboxylation takes place.) Therefore, it exists
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DINESH PUBLICATION-CARBOXYLIC ACIDS -ADDITIONAL IMPORTANT QUESTIONS
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  2. Why is acetyl chloride a better acetylating agent than acetic acid ?

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  3. Chloroformic acid does not exist while chloroethylformate exists. Expl...

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  4. Carbon-oxygen bond lengths in formic acid are different but are the sa...

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  6. Tertiary butyl benzene does not give benzoic acid when oxidised with K...

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  7. Fluorine is more electronegative than chlorine but p-fluorobenzoic aci...

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  8. CH(3)COO^(-) ion is more stable than C(2)H(5)O^(-) ion. Assign reason.

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  9. Peroxyacetic acid is a weaker acid than acetic acid. Explain.

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  10. Why are boiling of aldehydes and ketones lower than those of the corre...

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  11. Which out of each pair is expected to be a stornger acid ? (a) CH(3)...

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  12. What is glacial acetic acid ? Why is it so named ?

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  13. How will you prepare 2-methylbutanoic acid from butan-2-01 ?

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  14. How will you convert propionic acid to acetic acid ?

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  15. How will you prepare butanoic acid from 1-bromopropane?

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  16. Suggest an oxidising agent to convert (CH(3))(2)C=CHCOCH(3)" to "(CH(3...

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  17. Explain Why : (i) Carboxylic acids are stronger acids than alcohols....

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  18. How will you detect the presence of carboxyl group in a compound ?

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  19. Why is CH(2)=CH-COOH a stronger acid than CH(3)CH(2)COOH?

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  20. Out of but-3-enoic acid and but-3-yonic acid, which is a stronger acid...

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