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Compound Ph-O-overset(O)overset(||)(C)-P...

Compound `Ph-O-overset(O)overset(||)(C)-Ph` can be prepared by the reaction of _____________.

A

Phenol and benzoic acid in the presence of `NaOH`

B

Phenol and benzoyl chloride in the presence of pyridine

C

Phenol and benzoyl chloride in the presence of `ZnCl_(2)`

D

Phenol and benzaldehyde in the presence of palladium.

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The correct Answer is:
B
(b)
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The compound C_(6)H_(6)-O-overset(O)overset(||)C-C_(6)H_(5) can be prepared by the reaction of :

Ph-CH=CH-overset(O)overset(||)(C)-OH The IUPAC name is:

Treatement of compound Ph-O-overset(O)overset(||)(C)-Ph with NaOH solution yields

Mixuture of Ph-overset(O)overset(||)C-H and HCHO is treated with NaOH, then Cannizzaro reaction involves :

Ph-overset(O)overset(||)(C)-CH_(3)overset(PCI_(5))rarr Product is

Compound having -overset(O)overset(||)C-CH_(3) group reacts rapidly with halogen in presence of a base to form haloform . The reaction is known as haloform. R-overset(O)overset(||)C-CH_(3)overset(X_(2)+overset(Ө)OH)rarrR-overset(O)overset(||)C-overset(Ө)O+CHX_(3) Mechanism : Consider the following reactions : Reaction I rarr Ph-overset(O)overset(||)C-CH_(3)overset(Cl_(2),overset(Ө)OH)rarr Ph-overset(O)overset(||)C-overset(Ө)O+CHCl_(3) Reaction II rarr Ph-overset(O)overset(||)C-CD_(3)overset(Cl_(2)overset(Ө)OH)rarr,Ph-overset(O)overset(||)C-overset(Ө)O+CDCl_(3) Which of the following is correct comparison of the rate of reaction I and II ?

Ph-O-Meunderset("excess")overset(HI)rarr

DINESH PUBLICATION-CARBOXYLIC ACIDS -N.C.E.R.T. EXMPLAR PROBLEMS
  1. Which of the following compounds is most reactive towards nucleophilic...

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  2. The correct order of increasing acidic strength is

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  3. Compound Ph-O-overset(O)overset(||)(C)-Ph can be prepared by the react...

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  4. The reagent which does not react with both acetone and benzaldehyde is

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  5. Cannizzaro's reaction is not given by

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  6. Which product is formed when the compound is treated with concentrat...

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  7. CH(3) - C -= CHoverset(40%H(2)SO(4))underset(1%HgSO(4))rarrAoverset("i...

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  8. Compound A and C in the following reaction are CH(3)CHOoverset((i)CH(...

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  9. Which is the most suitable reagent for the following conversion ? CH...

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  10. Which of the following compound will give butanone on oxidation with a...

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  11. In Clemmensen reduction, carbonyl compound is treated with …….

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  12. Which of the following compounds do not undergo aldol condensation?

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  13. Treatement of compound Ph-O-overset(O)overset(||)(C)-Ph with NaOH so...

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  14. Which of the following conversion can be carried out by Clemmensen red...

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  15. Through which of the following reactions number of carbon atoms can be...

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  16. Benzophenone can be obtained by ……

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  17. Which of the following is the correct represetation for intermediate o...

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  18. Match the common names given in Column I with the IUPAC names given in...

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  19. Match the acids given in Column I with their correct IUPAC names given...

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  20. Match the reactions given in Column I with the suitable reagents given...

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