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Which is the most suitable reagent for t...

Which is the most suitable reagent for the following conversion ?
`CH_(3)-CH=CH-CH_(2)-overset(O)overset(||)(C)-CH_(3)to`
`CH_(3)-CH=CH-CH_(2)-overset(O)overset(||)(C)-OH`

A

Tollen's reagent

B

Benzoyl peroxide

C

`I_(2)" and "NaOH` solution

D

Sn and NaOH solution.

Text Solution

Verified by Experts

The correct Answer is:
C

(c) It is the most suitable reagent. The reaction is known as iodoform reaction in which methyl ketones `"("-overset(O)overset(||)C-CH_(3)")"`participate.
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CH_(3)Br-CH_(2)-overset(O)overset(||)(C)-CH_(2)CH_(3)

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The IUPAC name for CH_(3)-overset(O)overset(||)(C)-CH_(2)-CH_(2)-overset(O)overset(||)(C)-OH is :

Appropriate reducing agent for the following conversion is - CH_(2)=CH-CH_(2)-overset(O)overset(||)C-H rarr CH_(3)-CH_(@)-CH_(2)-CH_(2)OH

CH_(3)-underset(CH_(3))underset(|)(CH)-CH=CH-CH_(2)-overset(O)overset(||)(C)-OH

DINESH PUBLICATION-CARBOXYLIC ACIDS -N.C.E.R.T. EXMPLAR PROBLEMS
  1. The correct order of increasing acidic strength is

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  2. Compound Ph-O-overset(O)overset(||)(C)-Ph can be prepared by the react...

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  3. The reagent which does not react with both acetone and benzaldehyde is

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  4. Cannizzaro's reaction is not given by

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  5. Which product is formed when the compound is treated with concentrat...

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  6. CH(3) - C -= CHoverset(40%H(2)SO(4))underset(1%HgSO(4))rarrAoverset("i...

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  7. Compound A and C in the following reaction are CH(3)CHOoverset((i)CH(...

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  8. Which is the most suitable reagent for the following conversion ? CH...

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  9. Which of the following compound will give butanone on oxidation with a...

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  10. In Clemmensen reduction, carbonyl compound is treated with …….

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  11. Which of the following compounds do not undergo aldol condensation?

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  12. Treatement of compound Ph-O-overset(O)overset(||)(C)-Ph with NaOH so...

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  13. Which of the following conversion can be carried out by Clemmensen red...

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  14. Through which of the following reactions number of carbon atoms can be...

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  15. Benzophenone can be obtained by ……

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  16. Which of the following is the correct represetation for intermediate o...

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  17. Match the common names given in Column I with the IUPAC names given in...

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  18. Match the acids given in Column I with their correct IUPAC names given...

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  19. Match the reactions given in Column I with the suitable reagents given...

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  20. Match the example given in Column I with the name of the reaction in C...

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