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A compound [A] has the formula C(4)H(8)O...

A compound [A] has the formula `C_(4)H_(8)O_(2)`. When reacted with a Grignard reagent, `CH_(3)MgBr`, it takes up two molecules of it and upon acidification gives an alcohol [B]. The alcohol on reacting with Lucas reagent gives white coludiness on standing for sometime. When the alochol is oxidised, a compound [C] is produced with a pleasant smell. It neither reacts with Tollen's reagent, nor with Fehling's reagent.
The alcohol [B] is

A

a primary alcohol

B

a secondary alcohol

C

a tertiary alcohol

D

cannot be predicted from availabe information.

Text Solution

Verified by Experts

The correct Answer is:
B

(b) Alcohol [B] is a secondary alcohol `(CH_(3))_(2)CHOH` as it gives white cloudiness with Lucas reagent on standing.
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A compound [A] has the formula C_(4)H_(8)O_(2) . When reacted with a Grignard reagent, CH_(3)MgBr , it takes up two molecules of it and upon acidification gives an alcohol [B]. The alcohol on reacting with Lucas reagent gives white coludiness on standing for sometime. When the alochol is oxidised, a compound [C] is produced with a pleasant smell. It neither reacts with Tollen's reagent, nor with Fehling's reagent. The compound [A] is

A compound [A] has the formula C_(4)H_(8)O_(2) . When reacted with a Grignard reagent, CH_(3)MgBr , it takes up two molecules of it and upon acidification gives an alcohol [B]. The alcohol on reacting with Lucas reagent gives white coludiness on standing for sometime. When the alochol is oxidised, a compound [C] is produced with a pleasant smell. It neither reacts with Tollen's reagent, nor with Fehling's reagent. The compound [A] is

The alcohol which does not react with Lucas reagent is:

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The compound which reacts with hydroxylamine but does not react with Tollen's reagent is

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DINESH PUBLICATION-CARBOXYLIC ACIDS -MULTIPLE CHOICE QUESTION BANK (MCQB)
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  2. A compound [A] has the formula C(4)H(8)O(2). When reacted with a Grign...

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  3. A compound [A] has the formula C(4)H(8)O(2). When reacted with a Grign...

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  4. Carboxylic acids having at least one alpha-hydrogen react with Cl(2)" ...

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  5. Carboxylic acids having at least one alpha-hydrogen react with Cl(2) o...

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  6. Carboxylic acids having at least one alpha-hydrogen react with Cl(2) o...

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  7. The acidity of carboxylic acid is determined by the nature of the alky...

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  8. The acidity of carboxylic acid is determined by the nature of the alky...

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  9. The acidity of carboxylic acid is determined by the nature of the alky...

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  10. The acidity of carboxylic acid is determined by the nature of the alky...

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  11. Chlorination of toluene in the presence of light and heat followed by ...

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  12. Identify the final product of the following reaction :

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  13. Consider the following reaction underset("Ester(x)")underset()(C(4)H...

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  14. Which of the following carboxylic acids undergoes decarboxylation easi...

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  15. In the reaction C(6)H(5)CO OCH(3)overset(LiAlH(4))to? the products f...

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  16. The molecular weight of benzoic acid in benzene as determined by depre...

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  17. Which of the following compounds is most susceptible to a nucleophilic...

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  18. When propionic acid is treated with aqueous sodium bicarbonate, CO(2) ...

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  19. Ethyl easter overset(CH(3)MgBr)underset("excess")rarrP, the product P ...

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  20. When benzamide is treated with POCl(3) the product is

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