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Carboxylic acids having at least one alp...

Carboxylic acids having at least one `alpha`-hydrogen react with `Cl_(2)" or "Br_(2)` in the presnence of red phosphorus to give `alpha`-halo acids. The reaction is known as H.V.Z. reaction. The HVZ reaction is limited to the formation of `alpha`-chloro acid and `alpha`-bromo acid and it is sometimes difficult to carry out the reaction. Answer the following questions :
Which of the following carboxylic acids will not give HVZ reaction ?

A

`CH_(3)COOH`

B

`CH_(3)-overset(CH_(3))overset(|)CH-COOH`

C

`CH_(3)-CH_(2)-COOH`

D

`CH_(3)-overset(CH_(3))overset(|)underset(CH_(3))underset(|)C-COOH`

Text Solution

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The correct Answer is:
D

(d) The acid has no `alpha`-hydrogen atom.
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Carboxylic acids having at least one alpha -hydrogen react with Cl_(2) or Br_(2) in the presence of phosphorous to give alpha -halo acids. The reaction is known as Hell -volhar-Zelinsky reaction (HVZ reaction). R-CH_(2)-CO OH overset(P//Br_(2))underset(Delta)toR-CH(Br)CO OH The HVZ reaction is limited to the formation of alpha -chloro and alpha -bromo acids and it is sometimes backward to carry out. the reagents ( X_(2) and P ) are noxious and the reaction time is often long and the conditions of reaction are harsh. Which of the following carboxylic acids will not give HVZ reaction ?

Carboxylic acids having at least one alpha -hydrogen react with Cl_(2) or Br_(2) in the presence of phosphorous to give alpha -halo acids. The reaction is known as Hell -volhar-Zelinsky reaction (HVZ reaction). R-CH_(2)-CO OH overset(P//Br_(2))underset(Delta)toR-CH(Br)CO OH The HVZ reaction is limited to the formation of alpha -chloro and alpha -bromo acids and it is sometimes backward to carry out. the reagents ( X_(2) and P ) are noxious and the reaction time is often long and the conditions of reaction are harsh. Which of the following will be obtained when acetic acid is subjected to HVZ reaction ?

Carboxylic acids having at least one alpha -hydrogen react with Cl_(2) or Br_(2) in the presence of phosphorous to give alpha -halo acids. The reaction is known as Hell -volhar-Zelinsky reaction (HVZ reaction). R-CH_(2)-CO OH overset(P//Br_(2))underset(Delta)toR-CH(Br)CO OH The HVZ reaction is limited to the formation of alpha -chloro and alpha -bromo acids and it is sometimes backward to carry out. the reagents ( X_(2) and P ) are noxious and the reaction time is often long and the conditions of reaction are harsh. CH_(3)-CO OH overset(Br_(2)//P)to(A) overset(NaCN)to(B) overset(HOH//H^(+))to(C) The product (C) will be

Which of the following acids is not capable of undergoing HVZ reaction ?

Which reaction is suitable for the preparation of alpha -chloroacetic acid?

The carboxylic acid that does not undergo HVZ reaction is

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