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P and Q are isomers of dicarboxylic acid...

`P` and `Q` are isomers of dicarboxylic acid `C_(4)H_(4)O_(4)`. Bothdecolorize `Br_(2)//H_(2)O`. On heating, `P` forms the cyclic anhydride. Upon treatment with dilute alkaline `KMnO_(4),P` as well as `Q` could produce one or more than one forms `S,T` and `U`.
Compounds formed from `P` and `Q` are, respectively

A

Optically active S and optically active pair (T,U)

B

Optically inactive S and optically inactive pair (T,U)

C

Optically active pair (T,U) and optically active S

D

Optically inactive pair (T,U) and optically inactive S

Text Solution

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The correct Answer is:
A

(b) The compounds P and Q are unsaturated dicarboxylic acids :
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DINESH PUBLICATION-CARBOXYLIC ACIDS -MULTIPLE CHOICE QUESTION BANK (MCQB)
  1. The compound that undergoes decarboxylation most readily under mild c...

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  2. The major product(s) of the following reaction is (are)

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  3. P and Q are isomers of dicarboxylic acid C(4)H(4)O(4). Bothdecolorize ...

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  4. Among the following compounds, the one (s) that gives (gives) efferves...

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  5. The correct order of acidity for the following compounds is

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  6. The acids which do not contain a-COOH group are :

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  7. Phenol and benzoic acid may be distinguished by their reaction with :

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  8. Which of the following on oxidation with alkaline KMnO(4) followed by ...

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  9. Which of the following statements is/are correct about formic acid?

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  10. Assertion : Benzoic acid is a weaker acid than formic acid. Reason :...

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  11. Acetic acid does not undergo haloform reaction. Acetic acid has no a...

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  12. Assertion: Formic acid reduces mercuric chloride to mercurous chloride...

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  13. Assertion : Nitration of benzoic acid gives meta nitrobenzoic acid. ...

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  14. Assertion : Carbxoylic acids donot give characteristic reactions of ca...

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  15. Assertion : Upon heating an amide with Br(2)" and "KOH, primary amine ...

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  16. Assertion : Carboxylic acids are stronger acids than phenols. Reason...

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  17. Assertion : Although fluorine is more electronegative than chlorine, p...

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  18. Assertion : Acid amides are weakly basic in nature. Reason : Basic c...

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  19. Assertion: The pK(a) of acetic acid is lower than that of phenol. R...

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  20. Assertion: Formic acid reduces mercuric chloride to mercurous chloride...

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