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Predict in which of the following cases,...

Predict in which of the following cases, the reaction with Lucas reagent will be immediate, slow or will not take place at all room temperature ?

Text Solution

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(a) Structural formula represents a secondary alcohol. Therefore, it will give white turbidity with Lucas reagent after some time i.e. the reaction is slow.
(b) Structural formula is of a primary alcohol which gives white turbidity with Lucas reagent only upon heating.
(c) Structural formula is of a tertiary alcohol and it will give white turbidity with Lucas reagent immediately.
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Knowledge Check

  • Which of the following compound does not react with Lucas reagent ?

    A
    `(CH_3)_3C-CHO`
    B
    `(CH_3)_3C-OH`
    C
    `(CH_3)_2CH-OH`
    D
    `CH_3-OH`
  • Which of the following reacts first with Lucas reagent :

    A
    `C_(3)H_(7)OH`
    B
    `(CH_(3))_(2)CHOH`
    C
    `(CH_(3))_(3)COH`
    D
    `C_(6)H_(5)OH`
  • Which of the following will react faster with Lucas reagent ?

    A
    Butan-1-ol
    B
    Butan-2-ol
    C
    2-Methyl propane-2-ol
    D
    2-Methyl propane
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