Home
Class 12
CHEMISTRY
Draw the structure and the name of the p...

Draw the structure and the name of the product when the following alcohols are oxidised. Assume that the excess of oxidising agent is used.
(i) Butan-1-ol (ii) But-2-en-1-ol (iii) 2-Methylpropan-1-ol

Text Solution

Verified by Experts

The oxidation is generally carried with `KMnO_(4)` or `K_(2)Cr_(2)O_(7)` acidified with `H_(2)SO_(4)`.
(i) `underset("Butan-1-ol")(CH_(3)CH_(2)CH_(2)CH_(2)OH) overset("oxidation")(rarr) underset("Butanoic acid")(CH_(3)CH_(2)CH_(2)COOH)`
(ii) `underset("But-2-en-1-ol")(CH_(3)CH=CHCH_(2)OH) overset("oxidation")(rarr) underset("Ethanoic acid")(CH_(3)COOH)+underset("Ethanedioic acid")(HOOC COOH)`
(iii) `underset("2-Methylpropan-1-ol")(CH_(3)underset(CH_(3))underset(|)(CH)CH_(2)OH) overset("oxidation")(rarr) underset("2-Methylpropanoic acid")(CH_(3)underset(CH_(3))underset(|)(CH)COOH)`
Promotional Banner

Topper's Solved these Questions

  • ALCOHOLS AND PHENOLS

    DINESH PUBLICATION|Exercise HIGHER ORDER THINKING SKILLS|8 Videos
  • ALCOHOLS AND PHENOLS

    DINESH PUBLICATION|Exercise PROBLEM|9 Videos
  • ALCOHOLS AND PHENOLS

    DINESH PUBLICATION|Exercise ADDITIONAL IMPORTANT QUESTION|30 Videos
  • ALDEHYDES AND KETONES

    DINESH PUBLICATION|Exercise Interger|5 Videos

Similar Questions

Explore conceptually related problems

Draw the structrue and name the product formed if the following alcohols are oxidized. Assume that an excess of oxidising agent is used. (i) CH_(3)CH_(2)CH_(2)CH_(2)OH (ii) 2-butenol (iii) 2-methyl-1-propanol

Draw the structure of hex-1-en-3-ol compound.

Show how would you synthesize the following alcohols from ethyl lithium ? (i) Butan-1-ol, (ii) Butan-2-ol, (iii) 2-Methylbutan-2-ol, (iv) 3-Ethyl-2,4-dimethylpentan-3-ol.

Give chemical test to distinguish between : (i) Phenol and Benzyl alcohol. (ii) Butan-2-ol and 2-Methylpropan-2-ol.

Arrange the following in order of decreasing boiling points (i) Pentan-1-ol (ii) 2-Methylbutan-2-ol, (iii) 3-Methylbutan-2-ol.

Give structures of the products you would expect when each of the following alcohol reacts with (a) HCl –ZnCl_(2) (b) HBr and (c) SOCl_(2) . (i) Butan-1-ol (ii) 2-Methylbutan-2-ol

Give structures of the products you would expect when each of the following alcohols reacts with (a) HCl//ZnCl_(2) (b) HBr (c) SOCl_(2) : (i) Butan-1-ol (ii) 2-Methylbutan-2-ol

DINESH PUBLICATION-ALCOHOLS AND PHENOLS-QUESTION FROM BOARD EXAMINATION
  1. Explain the following with an example: i. Kolbe's reaction ii. R...

    Text Solution

    |

  2. Give the IUPAC names of : (i) CH(3)O-CH(2)-CH(2)-OCH(3) (ii) CH(3)-u...

    Text Solution

    |

  3. Draw the structure and the name of the product when the following alco...

    Text Solution

    |

  4. Alcohols are comparatively more soluble in water than hydrocarbons of ...

    Text Solution

    |

  5. An alkoxide ion is a stronger base than hydroxide ion. Justify.

    Text Solution

    |

  6. Write the mechanism for the preparation of ethanol from ethane.

    Text Solution

    |

  7. How will you convert methanol into ethanoic acid ?

    Text Solution

    |

  8. CH(3)CH(2)OH underset(443 K)overset(Conc. H(2)SO(4))(rarr) X+H(2)O C...

    Text Solution

    |

  9. How will you convert phenol to 2, 4, 6-trinitrophenol ?

    Text Solution

    |

  10. Arrange the following compounds in increasing of order of their acidic...

    Text Solution

    |

  11. How will you distinguish between benzyl alcohol and phenol ?

    Text Solution

    |

  12. Explain esterification reaction.

    Text Solution

    |

  13. Explain mechanism of dehysration of alcohols to give alkenes.

    Text Solution

    |

  14. Write any teo difference between methyl alcohol and ethyl alcohol.

    Text Solution

    |

  15. o- nitrophenol is steam volatile while p-nitrophenol is not. Discuss.

    Text Solution

    |

  16. Give the structures of A, B and C in the following reaction : CH(3)B...

    Text Solution

    |

  17. Name the reagents used in the following reactions: i. Oxidation of ...

    Text Solution

    |

  18. How will you prepare benzene from phenol ?

    Text Solution

    |

  19. How will you explain that phenols are acidic in nature ?

    Text Solution

    |

  20. How will you prepare alcohols from alkyl halides and alkenes ? Write c...

    Text Solution

    |