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A gas can be liquefied...

A gas can be liquefied

A

above its critical temperature

B

at its critical temperature

C

below its critical temperature

D

at any temperature

Text Solution

Verified by Experts

The correct Answer is:
C

A gas can only be liquefied below its critical temperature
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CO_(2) gas can be liquefied under pressure between

Boyle's temperature of four gases are given below: {:("Gases"," "A,B,C,D,),(T_(B),120K,25K,500K,410K,):} Which gas can be liquefied most easily ?

Seema visited a Natural Gas Compressing Unit and found that the gas can be liquefied under specific conditions of temperature and pressure . While sharing her experience with friends she got confused . Help her to identify the correct set of conditions.

The essential conditions for liquefaction of gases were discovered by Andrews in 1869 as a result of his study of pressure-volume-temperature relationship for CO_(2) . If was found that above a certain temperature, it was impossible to liquefy a gas whatever the pressure was applied. The temperature below which the gas can be liquefied by the application of pressure alone is called critical temperature (T_(c)) . The pressure required to liquefy a gas at this temperature is called the critical pressure (P_(c)) . The volume occupied by one mole of the substance at the critical temperature and pressure is called critcal volume. Critical constants are related with van der Waals' constant as follows: V_(c) = 3b, P_(c) = (a)/(27b^(2)), T_(c) = (8a)/(27 Rb) Gas A and can be liquefied at room temperature by applying pressure but gas B cannot. This reflects:

The essential conditions for liquefaction of gases were discovered by Andrews in 1869 as a result of his study of pressure-volume-temperature relationship for CO_(2) . If was found that above a certain temperature, it was impossible to liquefy a gas whatever the pressure was applied. The temperature below which the gas can be liquefied by the application of pressure alone is called critical temperature (T_(c)) . The pressure required to liquefy a gas at this temperature is called the critical pressure (P_(c)) . The volume occupied by one mole of the substance at the critical temperature and pressure is called critcal volume. Critical constants are related with van der Waals' constant as follows: V_(c) = 3b, P_(c) = (a)/(27b^(2)), T_(c) = (8a)/(27 Rb) The pressure required to liquefy a gas at the critical temperature is called :

The essential conditions for liquefaction of gases were discovered by Andrews in 1869 as a result of his study of pressure-volume-temperature relationship for CO_(2) . If was found that above a certain temperature, it was impossible to liquefy a gas whatever the pressure was applied. The temperature below which the gas can be liquefied by the application of pressure alone is called critical temperature (T_(c)) . The pressure required to liquefy a gas at this temperature is called the critical pressure (P_(c)) . The volume occupied by one mole of the substance at the critical temperature and pressure is called critcal volume. Critical constants are related with van der Waals' constant as follows: V_(c) = 3b, P_(c) = (a)/(27b^(2)), T_(c) = (8a)/(27 Rb) {:("Gases",A,B,C,D,),(P_(c) (atm),2.2,14,35,45,),(T_(c) (K),5.1,33,127,140,):} Which of the above gases cannot be liquefied at 100 K and 50 atm ?

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