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At 293 K, vapour pressure of pure benze...

At 293 K, vapour pressure of pure benzene is 75mm of Hg and that of pure toluene is 22 mm of Hg. The vapour pressure of the solution which contains 20 mol% benzene and 80 mol % toluene is

A

32.6 mm Hg

B

64.4 mm Hg

C

97 mm Hg

D

3.26 mm Hg

Text Solution

Verified by Experts

The correct Answer is:
A

`n_(Ben)=20%0.2`
`n_(Tol)=80%=0.8`
`P_(s)=X_(B)P_(B)^(@)+X_(T)P_(T)^(@)`
`P_(s)=0.2xx75+0.8xx22`
`=15.0+17.6`
`32.6`
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