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The reaction 2A+Bto product follow the m...

The reaction `2A+Bto` product follow the mechanism :-
`2AhArrA_(2)("fast")`
`A_(2)+BtoP(slow)`
`The order of the reaction is

A

1.5

B

3

C

1

D

2

Text Solution

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The correct Answer is:
To determine the order of the reaction given the mechanism, we can follow these steps: ### Step 1: Identify the Rate-Determining Step The slow step in the reaction mechanism is the rate-determining step. Here, the slow step is: \[ A_2 + B \rightarrow P \] ### Step 2: Write the Rate Law for the Slow Step The rate law for the slow step can be expressed as: \[ \text{Rate} = k[A_2][B] \] where \( k \) is the rate constant for this step. ### Step 3: Express \( [A_2] \) in Terms of \( [A] \) Since \( A_2 \) is formed from \( A \) in the fast step: \[ 2A \rightleftharpoons A_2 \] The equilibrium expression for this step can be written as: \[ K = \frac{[A_2]}{[A]^2} \] Thus, we can express \( [A_2] \) as: \[ [A_2] = K[A]^2 \] ### Step 4: Substitute \( [A_2] \) in the Rate Law Now, we can substitute \( [A_2] \) back into the rate law: \[ \text{Rate} = k[K[A]^2][B] \] This simplifies to: \[ \text{Rate} = k' [A]^2 [B] \] where \( k' = kK \) is a new rate constant. ### Step 5: Determine the Overall Order of the Reaction The overall order of the reaction is the sum of the powers of the concentration terms in the rate law: - The order with respect to \( A \) is 2. - The order with respect to \( B \) is 1. Thus, the overall order \( n \) is: \[ n = 2 + 1 = 3 \] ### Conclusion The order of the reaction is 3. ---

To determine the order of the reaction given the mechanism, we can follow these steps: ### Step 1: Identify the Rate-Determining Step The slow step in the reaction mechanism is the rate-determining step. Here, the slow step is: \[ A_2 + B \rightarrow P \] ### Step 2: Write the Rate Law for the Slow Step The rate law for the slow step can be expressed as: ...
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