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The value of n in the carbonyl is (CO)...

The value of n in the carbonyl is
`(CO)_(n)-Co-Co(CO)_(n)`

A

4

B

5

C

6

D

8

Text Solution

AI Generated Solution

The correct Answer is:
To find the value of \( n \) in the carbonyl compound represented as \( (CO)_{n}-Co-Co(CO)_{n} \), we can follow these steps: ### Step 1: Understanding the Structure The compound can be interpreted as having two cobalt (Co) atoms connected by a bridging carbonyl (CO) group. Each cobalt atom is also bonded to \( n \) carbonyl groups. ### Step 2: Analyzing the Carbonyl Groups In the structure \( (CO)_{n}-Co-Co(CO)_{n} \), we have: - One cobalt atom on the left connected to \( n \) carbonyl groups. - One cobalt atom on the right also connected to \( n \) carbonyl groups. ### Step 3: Applying the Effective Atomic Number (EAN) Rule The effective atomic number (EAN) rule states that the stability of a metal complex can be predicted by calculating the total number of electrons around the metal center. - The atomic number of cobalt (Co) is 27. - Each carbonyl (CO) contributes 2 electrons. ### Step 4: Calculating the Total Electron Count For one cobalt atom: - The contribution from \( n \) carbonyl groups is \( 2n \) electrons. - There is also 1 electron from the Co-Co bond. Thus, the total electron count for one cobalt atom can be expressed as: \[ \text{Total electrons} = 27 + 2n + 1 \] This should equal 36 (the stable electron count for cobalt). ### Step 5: Setting Up the Equation Setting the equation based on the EAN rule: \[ 27 + 2n + 1 = 36 \] ### Step 6: Solving for \( n \) Now, simplify the equation: \[ 28 + 2n = 36 \] Subtract 28 from both sides: \[ 2n = 8 \] Divide by 2: \[ n = 4 \] ### Conclusion Thus, the value of \( n \) in the carbonyl compound \( (CO)_{n}-Co-Co(CO)_{n} \) is **4**. ---

To find the value of \( n \) in the carbonyl compound represented as \( (CO)_{n}-Co-Co(CO)_{n} \), we can follow these steps: ### Step 1: Understanding the Structure The compound can be interpreted as having two cobalt (Co) atoms connected by a bridging carbonyl (CO) group. Each cobalt atom is also bonded to \( n \) carbonyl groups. ### Step 2: Analyzing the Carbonyl Groups In the structure \( (CO)_{n}-Co-Co(CO)_{n} \), we have: - One cobalt atom on the left connected to \( n \) carbonyl groups. ...
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