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IUPAC name of (C Cl(3))(3)C Cl is...

IUPAC name of `(C Cl_(3))_(3)C Cl` is

A

tris - trichloromethyl-1-chloro methane

B

2-Chloro-2-trischloromethyl propane

C

1,1,1,2,3,3,3-Heptachloro-2-trichloromethyl propane

D

1,1,1-trichloromethyl-1-chloro methane

Text Solution

AI Generated Solution

The correct Answer is:
To determine the IUPAC name of the compound \( (CCl_3)_3CCl \), we can follow these steps: ### Step 1: Identify the Structure The compound consists of a central carbon atom bonded to three \( CCl_3 \) groups and one \( Cl \) atom. This can be represented as follows: - The central carbon (C) is bonded to three trichloromethyl groups (\( CCl_3 \)). - There is also a chlorine atom (\( Cl \)) directly attached to the central carbon. ### Step 2: Count the Carbon Atoms The structure has: - 3 carbon atoms from the three \( CCl_3 \) groups. - 1 central carbon atom. Thus, the total number of carbon atoms is 4. ### Step 3: Determine the Parent Chain The longest continuous chain of carbon atoms contains 4 carbon atoms. Therefore, the parent chain is a butane. ### Step 4: Identify the Substituents The substituents on the butane chain are: - Three \( CCl_3 \) groups (trichloromethyl groups). - One \( Cl \) atom. ### Step 5: Number the Carbon Atoms To give the lowest numbers to the substituents, we number the carbon atoms in the chain: 1. The central carbon (C) is numbered as 1. 2. The three \( CCl_3 \) groups are attached to carbon 1. 3. The \( Cl \) atom is also attached to carbon 1. ### Step 6: Write the IUPAC Name Combining all the information: - The compound has one butane chain. - There are three \( CCl_3 \) groups and one \( Cl \) substituent. The IUPAC name can be written as: - 1,1,1-trichloro-2-chlorobutane. However, since all \( CCl_3 \) groups are on the same carbon, we can simplify this to: - 1,1,1-trichloro-2-chloropropane. ### Final Answer The IUPAC name of \( (CCl_3)_3CCl \) is **1,1,1-trichloro-2-chloropropane**. ---
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