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Out of the folowing paris of electorns, ...

Out of the folowing paris of electorns, identify the pairs of electrons present in degenrate orbitals.

A

in`=3,l=2,m_(1)=-2,m_(s)=-(1)/(2) iin=3,l=2,m_(1)=-1,m_(s)=-(1)/(2)`

B

`in=3,l=1,m_(1)=1,m_(s)=+(1)/(2) iin=3,l=2,m_(1)=1,=+(1)/(2)`

C

`i n=4,l=1,m_(1)=1,m_(s)=+(1)/(2) ii n=3,l=2,m_(1)=1,m_(s)=+(1)/(2)`

D

`in=3,l=2,m_(1)=+2,m_(s)=-(1)/(2) ii n=3,l=2,m_(1)=+2 ,m_(s)=+(1)/(2)`

Text Solution

Verified by Experts

Degenerate orbitals means the orbitals of the same subshell of the same main shell, i.e., their n and l value
(a) i `3d_(xy)` (ii) `3d(yz)`
(b) (i) `3p_( x)` (ii) `3d_(xy)`
(c) (i) `4s` (ii) `3d_(x y)`
(d) (i) `ed_(x^(2)-y^(2)` (ii) `3d_(x^(2)-y^(2)`
Thus `3d_(xy)` and `3d_(yz):3d_(x^(2)-y^(2)` and `3d_(x^(2)-y^(2))` represent pair of degonerate orbitals.
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