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In the following equilibria I:A+2B hA...

In the following equilibria
`I:A+2B hArr C, K_(eq)=K_(1)`
`II: C+DhArr 3A, K_(eq)=K_(2)`
`III, 6B+D hArr 2C, K_(eq)=K_(3)`
Hence,

A

`3K_(1)+K_(2)=K_(3)`

B

`K_(1)^(3).K_(2)^(2)=K_(3)`

C

`3K_(1)+K_(2)^(2)=K_(3)`

D

`K_(1)^(3).K_(2)=K_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the three given equilibrium reactions and their constants. We will derive the relationship between the equilibrium constants \( K_1 \), \( K_2 \), and \( K_3 \) based on the reactions provided. ### Step-by-Step Solution: 1. **Identify the Reactions and Their Equilibrium Constants:** - Reaction I: \( A + 2B \rightleftharpoons C \) with \( K_{eq} = K_1 \) - Reaction II: \( C + D \rightleftharpoons 3A \) with \( K_{eq} = K_2 \) - Reaction III: \( 6B + D \rightleftharpoons 2C \) with \( K_{eq} = K_3 \) 2. **Manipulate Reaction I:** - Multiply Reaction I by 3: \[ 3(A + 2B \rightleftharpoons C) \implies 3A + 6B \rightleftharpoons 3C \] - The equilibrium constant for this modified reaction becomes: \[ K_1^3 \] 3. **Combine the Modified Reaction I with Reaction II:** - We have the modified Reaction I: \[ 3A + 6B \rightleftharpoons 3C \quad (K_1^3) \] - And Reaction II: \[ C + D \rightleftharpoons 3A \quad (K_2) \] - To combine, we can reverse Reaction II: \[ 3A \rightleftharpoons C + D \quad (K_2^{-1}) \] 4. **Add the Two Reactions:** - Adding the modified Reaction I and the reversed Reaction II: \[ (3A + 6B \rightleftharpoons 3C) + (3A \rightleftharpoons C + D) \] - This results in: \[ 6B + D \rightleftharpoons 2C \] - The equilibrium constant for this combined reaction is: \[ K_3 = K_1^3 \cdot K_2^{-1} \] 5. **Rearranging the Equation:** - To express \( K_3 \) in terms of \( K_1 \) and \( K_2 \): \[ K_3 = \frac{K_1^3}{K_2} \] ### Conclusion: The relationship between the equilibrium constants is: \[ K_3 = \frac{K_1^3}{K_2} \]

To solve the problem, we need to analyze the three given equilibrium reactions and their constants. We will derive the relationship between the equilibrium constants \( K_1 \), \( K_2 \), and \( K_3 \) based on the reactions provided. ### Step-by-Step Solution: 1. **Identify the Reactions and Their Equilibrium Constants:** - Reaction I: \( A + 2B \rightleftharpoons C \) with \( K_{eq} = K_1 \) - Reaction II: \( C + D \rightleftharpoons 3A \) with \( K_{eq} = K_2 \) - Reaction III: \( 6B + D \rightleftharpoons 2C \) with \( K_{eq} = K_3 \) ...
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