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For the following reactions (1) , (2) an...

For the following reactions `(1) , (2)` and `(3)` equilibrium constants are given
`(1) CO_(2)(g) +H_(2)O(g) hArr CO_(2)(g) +H_(2)(g), K_(1)`
`(2) CH_(4)(g) +H_(2)O(g) hArr CO(g)+3H_(2)(g),K_(2)`
`(3) CH_(4)(g)+2H_(2)O(g) hArr CO_(2)(g)+4H_(2)(g), K_(3)`
Which of the following relation is correct ?

A

`K_(3)=K_(1) xx K_(2)`

B

`K_(3)K_(2)^(3)=K_(1)^(2)`

C

`K_(1) sqrt(K_(2))=K_(3)`

D

`K_(2)K_(3)=K_(1)`

Text Solution

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The correct Answer is:
To solve the problem, we need to analyze the given reactions and their equilibrium constants. ### Step 1: Write the expressions for the equilibrium constants 1. For reaction (1): \[ \text{CO}_2(g) + \text{H}_2O(g) \rightleftharpoons \text{CO}(g) + \text{H}_2(g) \] The equilibrium constant \( K_1 \) is given by: \[ K_1 = \frac{[\text{CO}][\text{H}_2]}{[\text{CO}_2][\text{H}_2O]} \] 2. For reaction (2): \[ \text{CH}_4(g) + \text{H}_2O(g) \rightleftharpoons \text{CO}(g) + 3\text{H}_2(g) \] The equilibrium constant \( K_2 \) is given by: \[ K_2 = \frac{[\text{CO}][\text{H}_2]^3}{[\text{CH}_4][\text{H}_2O]} \] 3. For reaction (3): \[ \text{CH}_4(g) + 2\text{H}_2O(g) \rightleftharpoons \text{CO}_2(g) + 4\text{H}_2(g) \] The equilibrium constant \( K_3 \) is given by: \[ K_3 = \frac{[\text{CO}_2][\text{H}_2]^4}{[\text{CH}_4][\text{H}_2O]^2} \] ### Step 2: Relate the reactions to find \( K_3 \) To find the relationship between \( K_1 \), \( K_2 \), and \( K_3 \), we can express \( K_3 \) in terms of \( K_1 \) and \( K_2 \). - We can combine reactions (1) and (2) to derive reaction (3): 1. **Reverse reaction (1)**: \[ \text{CO}(g) + \text{H}_2(g) \rightleftharpoons \text{CO}_2(g) + \text{H}_2O(g) \] The equilibrium constant for the reverse reaction is: \[ K_1' = \frac{1}{K_1} \] 2. **Add the reversed reaction (1) to reaction (2)**: \[ \text{CO}(g) + \text{H}_2(g) + \text{CH}_4(g) + \text{H}_2O(g) \rightleftharpoons \text{CO}_2(g) + \text{H}_2O(g) + 3\text{H}_2(g) \] This simplifies to: \[ \text{CH}_4(g) + 2\text{H}_2O(g) \rightleftharpoons \text{CO}_2(g) + 4\text{H}_2(g) \] The equilibrium constant for this combined reaction is: \[ K_3 = K_1' \cdot K_2 = \frac{1}{K_1} \cdot K_2 \] ### Step 3: Conclusion Thus, we can express \( K_3 \) as: \[ K_3 = \frac{K_2}{K_1} \] ### Final Relation The correct relation is: \[ K_3 = \frac{K_2}{K_1} \]

To solve the problem, we need to analyze the given reactions and their equilibrium constants. ### Step 1: Write the expressions for the equilibrium constants 1. For reaction (1): \[ \text{CO}_2(g) + \text{H}_2O(g) \rightleftharpoons \text{CO}(g) + \text{H}_2(g) \] ...
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For the following three reaction 1, 2 and 3, equilibrium constants are given: (1) CO_((g)) + H_(2)O_((g))hArrCO_(2(g)) + H_(2(g)), K_(1) (2) CH_(4(g)) + H_(2)O_((g))hArrCO_((g)) + 3H_(2(g)), K_(2) (3) CH_(4(g)) + 2H_(2)O_((g))hArrCO_(2(g)) + 4H_(2(g)), K_(3) Which of the following relations is correct ?

The equilibrium constant for the reaction a,b and c equilibrium constants are given : {:((A)CO(g)+H_2O(g)hArrCO_2(g)+H_2(g),,K_1),((B)CH_4(g)+H_2O(g)hArrCO(g)+3H_2(g),,K_2),(( C)CH_4(g)+2H_2O(g)hArrCO_2(g)+4H_2(g),,K_3):} Which of the following relations is correct ?

Consider the reaction :- 2CO(g)+2H_(2)O_((g))hArr2CO_(2(g))+2H_(2(g))eq.const=K_(1) CH_(4(g))+H_(2)O_((g))hArrCO_((g))+3H_(2(g)),eq.const=K_(2) CH_(4(g))+2H_(2)O_((g))hArrCO_(2(g))+4H_(2(g)),eq.const=K_(3) Which of the following ralation is correct ?

The relation between K_(p) and K_(c) is K_(p)=K_(c)(RT)^(Deltan) unit of K_(p)=(atm)^(Deltan) , unit of K_(c)=(mol L^(-1))^(Deltan) Consider the following reactions: i. CO(g)+H_(2)O(g) hArr CO_(2)(g)+H_(2)(g), K_(1) ii. CH_(4)(g)+H_(2)O(g) hArr CO(g)+3H_(2)(g), K_(2) iii. CH_(4)(g)+2H_(2)O(g) hArr CO_(2)(g)+4H_(2)(g), K_(3) Which of the following is correct?

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