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Which of the following are used to conve...

Which of the following are used to convert RCHO into `RCH_(2)OH` ?

A

`H_(2)//Pd`

B

`LiAlH_(4)`

C

`NaBH_(4)`

D

Reaction with RMgX followed by hydrolysis

Text Solution

Verified by Experts

The correct Answer is:
A, B, C

Conversion of aldehyde into alcohol is a reduction reaction. This reduction can be carried out by adding hydrogen in presence of finely deivided metal catalyst such as platinum palladium or nickel.
`RCHO+overset(H_(2)//Pd)rarr RCH_(2)OH`
It can also be prepared by using `NaBH_(4)` and `LiAlH_(4)` as a reducing agent.
`RCHO overset(NaBH_(4))rarr RCH_(2)OH`
`RCHO overset(LiAlH_(4))rarr RCH_(2)OH`
Reaction of RMgX with any aldehyde other than methanal gives secondary alcohols not the primary alcohols.

(Where, `R = -C_(2)H_(5), C_(3)H_(7)` etc.)
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NCERT EXEMPLAR-ALCOHOLS, PHENOLS AND ETHERS-Alcohols, Phenols And Ethers
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  3. Which of the following are used to convert RCHO into RCH(2)OH ?

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  6. Phenol can be distinguished from ethanol by the following reagents exc...

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  9. Write the IUPAC name of the following compounds. (a) CH(3)-underset(...

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  10. Write the IUPAC name of the compound given below. {:(CH(3)-CH(2)-C" ...

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  11. Name the factors responsible for the solubility of alcohols in water.

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  12. What is denatured alcohol ?

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  13. Suggest a reagent for the following conversion.

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  14. Out of 2-chloroethanol and ethanol which is more acidic and why ?

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  15. Suggest a reagent for conversion of ethanol to ethanal.

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  16. Suggest a reagent for conversion of ethanol to ethanoic acid.

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