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Which of the following are benzylic alco...

Which of the following are benzylic alcohols ?

A

`C_(6)H_(5)-CH_(2)-CH_(2)OH`

B

`C_(6)H_(5)-CH_(2)OH`

C

`C_(6)H_(5)-underset(CH_(3))underset(|)(CH)-OH`

D

`C_(6)H_(5)-CH_(2)-underset(CH_(3))underset(|)(CH)-OH`

Text Solution

Verified by Experts

The correct Answer is:
B, C

In benzylic alcohols, the -OH group is attached to a `sp^(3)` hybridised carbon atom next to an aromatic ring. In compound (a) and (d), the -OH group is attached to a `sp^(3)` hybridised carbon atom but this carbon is not attached to the benzene ring.
On the other hand, in compound (a) and (c), the -OH group is attached to a `sp^(3)` hibridised carbon atom next to an aromatic ring.
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  11. Suggest a reagent for conversion of ethanol to ethanal.

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  12. Suggest a reagent for conversion of ethanol to ethanoic acid.

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  14. Out of o-nitrophenol and o-cresol which is more acidic ?

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