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Arrange the following compounds in decre...

Arrange the following compounds in decreasing order of acidity.
`H_(2)O, ROH, HC -= CH`

Text Solution

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A stronger acid displaces a weaker acid from its salt. When RONa is treated with `H_(2)O`, it forms ROH, so water is a stronger acid than ROH.
`underset("Stronger acid")(HOH)+RONa rarr NaOH + underset("Weaker acid")(ROH)`
Similary, when sodium ethynide is treated with water and alcohol, then acetylene is obtained.
`underset("Stronger acid")(HOH)+CH-=CNa rarr underset("Weak acid")(HC -= CH)+NaOH`
`underset("Stronger acid")(ROH)+HC-=CNa rarr underset("Weak acid")(HC -= CH)+RONa`
Thus, water and aclohol are strongest acid than ethyne and the decreasing order of acidity of given compounds are
`HOH gt ROH gt HC -= CH`
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Knowledge Check

  • Arrange the following compounds in the decreasing order of acidity.

    A
    `H_2O gt HC-=CH gt ROH`
    B
    `H_2O gt ROH gt HC-=CH`
    C
    `HC-=CH gt ROH gt H_2O`
    D
    `HC-=CH gt H_2O . ROH`
  • Arrange the following compounds in decreasing order of basicity :

    A
    `PgtQgtRgtS`
    B
    `QgtPgtRgtS`
    C
    `RgtSgtQgtP`
    D
    `QgtPgtSgtR`
  • Arrange the following compounds in decreasing order of acidity : CH_(3)CH_(2)OH H_(2)C=CH_(2)

    A
    `RgtQgtPgtS`
    B
    `QgtRgtPgtS`
    C
    `SgtRgtQgtP`
    D
    `QgtPgtRgtS`
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