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Preparation of alcohols from alkenes inv...

Preparation of alcohols from alkenes involves the electrophilic attack on alkene carbon atom. Explain its mechanism.

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Preparation of alcohols from alkene by the hydration of alkenes in presence of sulphuric acid.
`CH_(2)=CH_(2)+H_(2)O overset(H^(+))rarrCH_(3)CH_(2)OH`
This addition reaction takes place in accordance with Markownikoff's rule.
Mechanism The mechanism of the reaction involves the following three steps
Step 1 Protonation of alkene to form carbocation by electrophilic attack to `H_(3)^(+)O`.

Step 2 Attack of water molecule to the secondary carbocation.

Step 3 Loss of the hydrogen from the protonated alcohol.
`-overset(|)underset(|)(C)-overset(|)underset(|)(C)-overset(H)overset(| o+)(O)-H+H_(2)ddot(underset("..")(O))to-overset(H)overset(|)underset(|)(C)-overset(":"ddot(O)H)overset(|)underset(|)(C)-+H_(3)underset("..")(O^(o+))`
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NCERT EXEMPLAR-ALCOHOLS, PHENOLS AND ETHERS-Alcohols, Phenols And Ethers
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  4. Explain why is O=C=O non polar while R-O-R is polar ?

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  9. Dipole moment of phenol is smaller than that of methanol. Why ?

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  10. Ethers can be prepared by Williamson synthesis in which an alkyl halid...

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  11. Why is the C-O-H bond angle in alcohols slightly less than the tetrahe...

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  12. Explain why low molecular mass alcohols are soluble in water ?

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  18. Match the starting material given in Column I with the products formed...

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  19. Match the items of Column I with items of Column II.

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  20. Match the items of Column I with items of Column II.

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