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Explain why p-nitrophenol is more acidic...

Explain why p-nitrophenol is more acidic than phenol ?

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To explain why p-nitrophenol is more acidic than phenol, we can follow these steps: ### Step 1: Understand the Structures - **Phenol** is a simple aromatic compound with a hydroxyl (-OH) group attached to a benzene ring. - **p-Nitrophenol** has a nitro (-NO2) group attached to the benzene ring at the para position relative to the hydroxyl group. ### Step 2: Identify the Role of the Nitro Group - The nitro group is an electron-withdrawing group due to its strong electronegativity and resonance effects. This means it pulls electron density away from the rest of the molecule. ...
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Assertion (A) p-nitrophenol is more acidic than phenol. Reason (R) Nitro group helps in the stabilisation of the phenoxide ion by dispersal of negative charge due to resonance.

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NCERT EXEMPLAR-ALCOHOLS, PHENOLS AND ETHERS-Alcohols, Phenols And Ethers
  1. Why is the C-O-H bond angle in alcohols slightly less than the tetrahe...

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  2. Explain why low molecular mass alcohols are soluble in water ?

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  3. Explain why p-nitrophenol is more acidic than phenol ?

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  4. Explain why alcohols and ethers of comparable molecular mass have diff...

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  5. The carbon-oxygen bond in phenol is slightly stronger than that in met...

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  6. Arrange water, ethanol and phenol in increasing order of acidity and g...

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  7. Match the structures of the compounds given in Column I with the name ...

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  8. Match the starting material given in Column I with the products formed...

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  9. Match the items of Column I with items of Column II.

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  10. Match the items of Column I with items of Column II.

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  11. Assertion (A) Addition reaction of water to but-1-ene in acidic medium...

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  12. Assertion (A) p-nitrophenol is more acidic than phenol. Reason (R) N...

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  13. Assertion (A) IUPAC name of the compound CH(3)-underset(CH(3))unders...

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  14. Assertion (A) Bond angle is ethers is slightly less than tetrahedral a...

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  15. Assertion (A) Boiling points of alcohols and ethers are high. Reason...

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  16. Assertion (A) Like bromination of benzene, bromination of phenol is al...

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  17. Assertion (A) o-nitrophenol is less soluble in water than the m and p-...

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  18. Assertion (A) Ethanol is a weaker acid than phenol. Reason (R) Sodiu...

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  19. Assertion (A) Phenol forms 2, 4, 6-tribromophenol o treatement with Br...

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  20. Assertion (A) Phenols give o-and p-nitrophenol on nitration with conc....

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